<生产厂家价格>

O-乙基硫代磷酰二氯

O-乙基硫代磷酰二氯用途

O-乙基硫代磷酰二氯简称乙基二氯化物，用于合成有机磷杀虫剂异丙胺磷(乙基异柳磷)及除草剂胺草磷、抑草磷

O-乙基硫代磷酰二氯名称

[ CAS 号 ]:
1498-64-2

[ 中文名 ]:
二氯硫代磷酸乙酯

[ 英文名 ]:
ethyl dichlorothiophosphate

[中文别名 ]:

[英文别名 ]:

ethoxythiophosphoric acid dichloride
Ethyl phosphonodichloridothionate
MFCD00004915
Ethyl dichlorothiophosphate
Ethyl phosphorodichloridothionate
O-ethyl thiophosphorodichloridate
Phosphine sulfide,dichloroethoxy
Ethyl thiophosphorodichloridate
Ethylphosphorothioic dichloride
O-Ethyl phosphorothiodichloridate

O-乙基硫代磷酰二氯物理化学性质

[ 密度 ]:
1.458g/cm3

[ 沸点 ]:
180.5ºC at 760mmHg

[ 分子式 ]:
C₂H₅Cl₂OPS

[ 分子量 ]:
179.00500

[ 闪点 ]:
63ºC

[ 精确质量 ]:
177.91800

[ PSA ]:
51.13000

[ LogP ]:
3.37560

[ 蒸汽压 ]:
1.21mmHg at 25°C

[ 折射率 ]:
n20/D 1.504(lit.)

O-乙基硫代磷酰二氯MSDS

O-乙基硫代磷酰二氯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TD4400000

CHEMICAL NAME :: Phosphorodichloridothioic acid, O-ethyl ester

CAS REGISTRY NUMBER :: 1498-64-2

BEILSTEIN REFERENCE NO. :: 1702237

LAST UPDATED :: 199710

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C2-H5-Cl2-O-P-S

MOLECULAR WEIGHT :: 179.00

WISWESSER LINE NOTATION :: SPGGO2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 900 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Gastrointestinal - changes in structure or function of salivary glands Blood - hemorrhage

REFERENCE :: HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 33(10-12),334,1968

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 32 ppm/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1171,1986

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 720 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Gastrointestinal - changes in structure or function of salivary glands Blood - hemorrhage

REFERENCE :: HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 33(10-12),334,1968

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 3060 mg/m3/10M

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,NOV1942

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 850 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Gastrointestinal - changes in structure or function of salivary glands Blood - hemorrhage

REFERENCE :: HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 33(10-12),334,1968

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 750 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Gastrointestinal - changes in structure or function of salivary glands Blood - hemorrhage

REFERENCE :: HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 33(10-12),334,1968

O-乙基硫代磷酰二氯安全信息

[ 符号 ]:

GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H311-H314-H331

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T: Toxic;

[ 风险声明 (欧洲) ]:
23/24/25-34

[ 安全声明 (欧洲) ]:
S22;S26;S45;S36/S37/S39

[ 危险品运输编码 ]:
UN 3390 6.1/PG 1

[ WGK德国 ]:
3

[ RTECS号 ]:
TD4400000

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1(a)

[ 海关编码 ]:
2931900090

O-乙基硫代磷酰二氯合成路线

O-乙基硫代磷酰二氯上下游产品

O-乙基硫代磷酰二氯上游产品

O-乙基硫代磷酰二氯下游产品

O-乙基硫代磷酰二氯制备

其制备方法是将新鲜的三氯硫磷计量加入反应釜，冷却到-2℃，慢慢滴加无水乙醇，控制反应温度(0±2)℃，反应中带负压，抽去生成的氯化氢，反应完毕移至蒸馏釜，先蒸出前馏分，继续蒸馏得产品。

O-乙基硫代磷酰二氯海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%