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2,2'-[4-(2-羟基乙氨基)-3-硝基苯亚氨基]二乙醇胺

用途

【用途一】
用作医药、染料中间体

名称

[ CAS 号 ]:
33229-34-4

[ 中文名 ]:
3-硝基-4-羟乙氨基-N,N-二羟乙基苯胺

[ 英文名 ]:
2,2'-[4-(2-Hydroxyethylamino)-3-nitrophenylimino]diethanol

[中文别名 ]:

[英文别名 ]:

2,2'-(4-(2-hydroxyethylamino)-3-nitro-phenylimino
EINECS 251-410-3
HC Blue no. 2
MFCD00071762
HC BLUE #2

物理化学性质

[ 密度 ]:
1.421 g/cm3

[ 沸点 ]:
582.7ºC at 760 mmHg

[ 熔点 ]:
108-111 °C(lit.)

[ 分子式 ]:
C₁₂H₁₉N₃O₅

[ 分子量 ]:
285.29600

[ 精确质量 ]:
285.13200

[ PSA ]:
121.78000

[ LogP ]:
0.38620

[ 外观性状 ]:
暗蓝色至暗棕色微结晶粉末

[ 折射率 ]:
1.672

[ 储存条件 ]:
室温，密封，干燥

MSDS

详细MSDS(安全技术说明书)

毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: KL2880000

CHEMICAL NAME :: Ethanol, 2,2'-((4-((2-hydroxyethyl)amino)-3-nitrophenyl)imino) di-

CAS REGISTRY NUMBER :: 33229-34-4

LAST UPDATED :: 199612

DATA ITEMS CITED :: 17

MOLECULAR FORMULA :: C12-H19-N3-O5

MOLECULAR WEIGHT :: 285.34

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >1 gm/kg

TOXIC EFFECTS :: Kidney, Ureter, Bladder - other changes in urine composition

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 17500 mg/kg/14D-C

TOXIC EFFECTS :: Kidney, Ureter, Bladder - other changes in urine composition Nutritional and Gross Metabolic - weight loss or decreased weight gain

MUTATION DATA

TYPE OF TEST :: Unscheduled DNA synthesis

TEST SYSTEM :: Rodent - rabbit Liver

DOSE/DURATION :: 50 mg/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 241,145,1990 *** REVIEWS *** IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,143,1993 IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,143,1993 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,143,1993

安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
1

[ RTECS号 ]:
KL2880000

[ 海关编码 ]:
2922199090

上下游产品

上游产品

下游产品

海关

[ 海关编码 ]: 2922199090

[ 中文概述 ]:
2922199090. 其他氨基醇及其醚，酯和它们的盐（但含一种以上含氧基的除外）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装

[ Summary ]:
2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

文献

Self-Healing Supramolecular Polymers In Action. van Gemert GML, et al.

Macromol. Chem. Phys. 213(2) , 234-42, (2012)

NTP Toxicology and Carcinogenesis Studies of HC Blue No. 2 [2,2'-((4-((2-Hydroxyethyl)amino)-3-nitrophenyl)imino)bis(ethanol)] (CAS No. 33229-34-4) in F344/N Rats and B6C3F 1 Mice (Feed Studies).

Natl. Toxicol. Program Tech. Rep. Ser. 293 , 1-192, (1985)

Toxicology and carcinogenesis studies of HC Blue No. 2 (approximately 98% pure), a semipermanent hair dye, were conducted by administering the test chemical in feed for 103 weeks to groups of 50 F344/...

HC Blue No. 2.

IARC Monogr. Eval. Carcinog. Risks Hum. 57 , 143-51, (1993)

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