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N-甲基-1,2-苯二胺

N-甲基-1,2-苯二胺用途

【用途一】
用作医药及染料中间体

N-甲基-1,2-苯二胺名称

[ CAS 号 ]:
4760-34-3

[ 中文名 ]:
N-甲基-1,2-苯二胺

[ 英文名 ]:
n-methylbenzol-1,2-diamin

[中文别名 ]:

[英文别名 ]:

1,2-Benzenediamine, N1-methyl-
N-Methylbenzene-1,2-diamine
N-Methyl-1,2-benzenediamine
n-methylbenzol-1,2-diamin
N-Methyl-1,2-phenylenediamine
N1-Methylbenzene-1,2-diamine
EINECS 225-297-6
2-N-methylbenzene-1,2-diamine
1,2-Benzenediamine, N-methyl-
MFCD00192314

N-甲基-1,2-苯二胺物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
252.4±23.0 °C at 760 mmHg

[ 熔点 ]:
22 °C(lit.)

[ 分子式 ]:
C₇H₁₀N₂

[ 分子量 ]:
122.168

[ 闪点 ]:
122.4±26.2 °C

[ 精确质量 ]:
122.084396

[ PSA ]:
38.05000

[ LogP ]:
0.64

[ 外观性状 ]:
黄色至红色至暗棕色液体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.641

[ 储存条件 ]:
室温

N-甲基-1,2-苯二胺MSDS

详细MSDS(安全技术说明书)

N-甲基-1,2-苯二胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: ST2770000

CHEMICAL NAME :: o-Phenylenediamine, N-methyl-

CAS REGISTRY NUMBER :: 4760-34-3

BEILSTEIN REFERENCE NO. :: 0636586

LAST UPDATED :: 199712

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C7-H10-N2

MOLECULAR WEIGHT :: 122.19

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 2500 ug/plate

REFERENCE :: FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 23,695,1985

N-甲基-1,2-苯二胺安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H312-H315-H319-H332

[ 警示性声明 ]:
P280-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R20/21/22;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
ST2770000

[ 海关编码 ]:
2921590090

N-甲基-1,2-苯二胺上下游产品

N-甲基-1,2-苯二胺上游产品

N-甲基-1,2-苯二胺下游产品

N-甲基-1,2-苯二胺海关

[ 海关编码 ]: 2921590090

[ 中文概述 ]:
2921590090. 其他芳香多胺及衍生物及它们的盐. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

N-甲基-1,2-苯二胺文献

Modification of carbon electrode with aryl groups having an aliphatic amine by electrochemical reduction of in situ generated diazonium cations.

Langmuir 24(16) , 8711-8, (2008)

The electrochemically induced functionalization of glassy carbon electrode by aryl groups having an aliphatic amine group was achieved by reduction of in situ generated diazonium cations in aqueous me...

1-Methyl-1H-benzimidazole-2(3H)-thione.

Acta Crystallogr. Sect. E Struct. Rep. Online 64(Pt 6) , o1141, (2008)

The title compound, C(8)H(8)N(2)S, was prepared by the condensation of N-methyl-1,2-phenyl-enediamine and carbon disulfide. The crystal structure is stabilized by a C-H⋯π inter-action between a benzen...

Efficient and improved synthesis of Telmisartan.

Beilstein J. Org. Chem. 6 , 25, (2010)

An efficient synthesis of the angiotensin II receptor antagonist Telmisartan (1) is presented involving a cross coupling of 4-formylphenylboronic acid 10 with 2-(2-bromophenyl)-4,4-dimethyl-2-oxazolin...

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