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三苯基氯硅烷

三苯基氯硅烷用途

【用途一】
用于制药及有机合成
【用途二】
制药和有机合成中间体。
【用途三】
硅烷化试剂。制药和有机合成中间体。

三苯基氯硅烷名称

[ CAS 号 ]:
76-86-8

[ 中文名 ]:
三苯基氯硅烷

[ 英文名 ]:
Chlorotriphenylsilane

[中文别名 ]:

[英文别名 ]:

Benzene, 1,1',1''-(chlorosilylidyne)tris-
Triphenylsilyl chloride
Chloro(triphenyl)silane
Chlorotriphenylsilane
triphenylsilylchloride
Triphenylchlorosilane
EINECS 200-989-0
MFCD00000496

三苯基氯硅烷物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
374.8±15.0 °C at 760 mmHg

[ 熔点 ]:
91-94 °C(lit.)

[ 分子式 ]:
C₁₈H₁₅ClSi

[ 分子量 ]:
294.850

[ 闪点 ]:
164.5±10.3 °C

[ 精确质量 ]:
294.063141

[ LogP ]:
7.43

[ 外观性状 ]:
白色粉末

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
1.614

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、碱类、潮湿物分开存放

[ 水溶解性 ]:
acetone: 0.1 g/mL, clear

三苯基氯硅烷MSDS

三苯基氯硅烷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: VV2720000

CHEMICAL NAME :: Silane, chlorotriphenyl-

CAS REGISTRY NUMBER :: 76-86-8

BEILSTEIN REFERENCE NO. :: 1820487

LAST UPDATED :: 199709

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C18-H15-Cl-Si

MOLECULAR WEIGHT :: 294.87

WISWESSER LINE NOTATION :: G-SI-R&R&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 56 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04717 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4623 No. of Facilities: 4 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 280 (estimated) No. of Female Employees: 4 (estimated)

三苯基氯硅烷安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314-H335

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S24/25

[ 危险品运输编码 ]:
UN 3261 8/PG 2

[ WGK德国 ]:
1

[ RTECS号 ]:
VV2720000

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
29310095

三苯基氯硅烷合成路线

三苯基氯硅烷上下游产品

三苯基氯硅烷上游产品

三苯基氯硅烷下游产品

三苯基氯硅烷海关

[ 海关编码 ]: 29310095

三苯基氯硅烷文献

[Preparation of phenyl treated packing materials for high-performance liquid chromatography: evaluation by retention behaviour of carbamazepine and diphenylhydantoin].

Yakugaku Zasshi 112(6) , 409-13, (1992)

The retention behavior and selectivity of 30 kinds of phenyl-modified porous glasses and silicas, prepared from solutions of phenyldimethylchlorosilane, diphenylmethylchlorosilane or triphenylchlorosi...

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