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三丁氧基乙基磷酸酯

三丁氧基乙基磷酸酯用途

【用途一】
本品为阻燃性增塑剂，主要用于聚氨酯橡胶、纤维素、聚乙烯醇等的阻燃和增塑，具有良好的低温特点。

三丁氧基乙基磷酸酯名称

[ CAS 号 ]:
78-51-3

[ 中文名 ]:
磷酸三(丁氧基乙基)酯

[ 英文名 ]:
Tris(2-butoxyethyl) phosphate

[中文别名 ]:

[英文别名 ]:

KP 140
Tributyl cellosolve phosphate
Phosphoric acid, tributoxyethyl ester
Phosflex T-bep
Ethanol,2-butoxy-,phosphate (3:1)
tris(2-butoxy-ethyl)phosphate
Tributoxyethyl phosphate
Tris-(2-butoxyethyl)fosfat [Czech]
Tris(2-buthoxyethyl) phosphate
Phosphoric acid, tris(2-butoxyethyl) ester

三丁氧基乙基磷酸酯物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
413.9±0.0 °C at 760 mmHg

[ 熔点 ]:
-70°C

[ 分子式 ]:
C₁₈H₃₉O₇P

[ 分子量 ]:
398.472

[ 闪点 ]:
241.5±47.7 °C

[ 精确质量 ]:
398.243347

[ PSA ]:
82.26000

[ LogP ]:
4.30

[ 外观性状 ]:
黏的无色或略黄色液体

[ 蒸汽密度 ]:
13.7 (vs air)

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.443

[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开储运存放

[ 稳定性 ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
Soluble

三丁氧基乙基磷酸酯MSDS

三丁氧基乙基磷酸酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: KJ9800000

CAS REGISTRY NUMBER :: 78-51-3

BEILSTEIN REFERENCE NO. :: 1716010

LAST UPDATED :: 199710

DATA ITEMS CITED :: 17

MOLECULAR FORMULA :: C18-H39-O7-P

MOLECULAR WEIGHT :: 398.54

WISWESSER LINE NOTATION :: 4O2OPO&O2O4&O2O4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1142,1986

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1142,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NPIRI* Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. (National Assoc. of Printing Ink Research Institute, Francis McDonald Sinclair Memorial Laboratory, Lehigh Univ., Bethlehem, PA 18015) Volume(issue)/page/year: 2,93,1975

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 180 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00391

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >16 mL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 3 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 29ZWAE "Practical Toxicology of Plastics," Lefaux, R., Cleveland, OH, Chemical Rubber Co., 1968 Volume(issue)/page/year: -,336,1968

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - chicken

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - phosphatases

REFERENCE :: TIHEEC Toxicology and Industrial Health. (Princeton Scientific Pub. Co., POB 2155, Princeton, NJ 08540) V.1- 1985- Volume(issue)/page/year: 6,415,1990 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 22500 uL/kg/18W-I

TOXIC EFFECTS :: Peripheral Nerve and Sensation - sensory change involving peripheral nerve Peripheral Nerve and Sensation - recording from peripheral motor nerve Peripheral Nerve and Sensation - structural change in nerve or sheath

REFERENCE :: JJATDK JAT, Journal of Applied Toxicology. (John Wiley & Sons Ltd., Baffins Lane, Chichester, W. Sussex PO19 1UD, UK) V.1- 1981- Volume(issue)/page/year: 4,42,1984

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 216 gm/kg/14W-C

TOXIC EFFECTS :: Liver - changes in liver weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other transferases

REFERENCE :: JTSCDR Journal of Toxicological Sciences. (Japanese Soc. of Toxicological Sciences, 4th Floor, Gakkai Center Bldg., 4-16, Yayoi 2-chome, Bunkyo-ku, Tokyo 113, Japan) V.1- 1976- Volume(issue)/page/year: 18,421,1993

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 15680 uL/kg/14D-I

TOXIC EFFECTS :: Peripheral Nerve and Sensation - recording from afferent nerve

REFERENCE :: CMSHAF Chemosphere. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.1- 1972- Volume(issue)/page/year: 13,801,1984

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 15 gm/kg/3W-I

TOXIC EFFECTS :: Skin and Appendages - dermatitis, other (after systemic exposure)

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0528536 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3;Skin JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83871 No. of Facilities: 18954 (estimated) No. of Industries: 136 No. of Occupations: 50 No. of Employees: 184722 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83871 No. of Facilities: 9701 (estimated) No. of Industries: 90 No. of Occupations: 55 No. of Employees: 257421 (estimated) No. of Female Employees: 105777 (estimated)

三丁氧基乙基磷酸酯安全信息

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful

[ 风险声明 (欧洲) ]:
R20/21/22;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
1

[ RTECS号 ]:
KJ9800000

[ 海关编码 ]:
2920901900

三丁氧基乙基磷酸酯合成路线

三丁氧基乙基磷酸酯上下游产品

三丁氧基乙基磷酸酯上游产品

三丁氧基乙基磷酸酯下游产品

三丁氧基乙基磷酸酯海关

[ 海关编码 ]: 2920901900

[ 中文概述 ]:
2920901900 亚磷酸酯。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2920901900 VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

三丁氧基乙基磷酸酯文献

Elucidating toxicological mechanisms of current flame retardants using a bacterial gene profiling assay.

Toxicol. In Vitro 29 , 2124-32, (2015)

Flame retardants are ubiquitously used chemicals that have been shown to contaminate environments. Toxicological data is largely limited, with little insight into their molecular modes of action that ...

Organophosphate flame retardants and organosiloxanes in predatory freshwater fish from locations across Canada.

Environ. Pollut. 193 , 254-61, (2014)

Whole body homogenates of Lake Trout (Salvelinus namaycush) or Walleye (Sander vitreus) collected from Canadian lakes were screened for organophosphate flame retardant (OPFR) and organosiloxane compou...

Levels and distributions of organophosphate flame retardants and plasticizers in sediment from Taihu Lake, China.

Environ. Toxicol. Chem. 31(7) , 1478-84, (2012)

The concentrations and distribution of seven organophosphate flame retardants and plasticizers (OPs) were investigated in 28 sediment samples collected from Taihu Lake. The analytes were ultrasonicall...

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