1-(溴乙酰)芘

1-(溴乙酰)芘用途

1-(Bromoacetyl)pyrene (BAP)[8]is a pyrene derivative. It has been synthesized by reacting cupric bromide with 1-acetylpyrene.Studies suggest that the introduction of a bromoacetyl chromophoric moiety to pyrene drastically increases the photoinitiating efficiency of pyrenes.

1-(溴乙酰)芘名称

[ CAS 号 ]:
80480-15-5

[ 中文名 ]:
1-(溴乙酰)芘

[ 英文名 ]:
2-Bromo-1-(1-pyrenyl)ethanone

[中文别名 ]:

1-(溴乙酰基)芘

[英文别名 ]:

2-bromo-1-pyren-1-ylethanone
MFCD00191839
2-Bromo-1-(1-pyrenyl)ethanone
Ethanone, 2-bromo-1-(1-pyrenyl)-

1-(溴乙酰)芘物理化学性质

[ 密度 ]:
1.6±0.1 g/cm3

[ 沸点 ]:
476.7±18.0 °C at 760 mmHg

[ 熔点 ]:
129-131ºC(lit.)

[ 分子式 ]:
C₁₈H₁₁BrO

[ 分子量 ]:
323.183

[ 闪点 ]:
109.3±8.5 °C

[ 精确质量 ]:
321.999329

[ PSA ]:
17.07000

[ LogP ]:
5.14

[ 外观性状 ]:
黄色至橙色至棕色粉末,晶体

[ 蒸汽压 ]:
0.0±1.2 mmHg at 25°C

[ 折射率 ]:
1.823

[ 储存条件 ]:
室温

1-(溴乙酰)芘MSDS

详细MSDS(安全技术说明书)

1-(溴乙酰)芘安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314-H413

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C: Corrosive;

[ 风险声明 (欧洲) ]:
R34

[ 安全声明 (欧洲) ]:
22-26-36/37/39-45

[ 危险品运输编码 ]:
UN 1759 8

[ 海关编码 ]:
2914700090

1-(溴乙酰)芘合成路线

详细合成路线

1-(溴乙酰)芘上下游产品

1-(溴乙酰)芘上游产品

1-(溴乙酰)芘下游产品

1-(溴乙酰)芘海关

[ 海关编码 ]: 2914700090

[ 中文概述 ]:
2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

1-(溴乙酰)芘文献

Li⁺ selective podand-type fluoroionophore based on a diphenyl sulfoxide derivative bearing two pyrene groups.

Molecules 16(8) , 6844-57, (2011)

New podand-type fluoroionophores having two pyrene moieties: 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfide (3), 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfoxide (4), and 2,2´-bis(1-pyrenylacetyloxy)diphe...

Probing solution behaviour of metallosupramolecular complexes using pyrene fluorescence.

Dalton Trans. 41(5) , 1568-73, (2012)

A new method for assessing the topology of metallosupramolecular assemblies using pyrene-appended ligands is reported. Two potentially tetradentate ligands containing one (L(1)) and two (L(2)) termina...

In vitro bio-immunological and cytotoxicity studies of poly(2-oxazolines).

J. Mater. Sci. Mater. Med. 22(7) , 1725-34, (2011)

Poly(2-oxazolines) with varying alkyl chain lengths (e.g., methyl, ethyl, aryl) and molar masses have been tested for cell cytotoxicity in vitro. A standard 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenylte...

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