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吩嗪

吩嗪用途

【用途一】
主要用于染料、医药、有机合成中间体及生化研究

吩嗪名称

[ CAS 号 ]:
92-82-0

[ 中文名 ]:
酚嗪

[ 英文名 ]:
Phenazine

[中文别名 ]:

[英文别名 ]:

acridizine
Phenazine
MFCD00005023
dibenzopyrazine
dibenzo-p-diazine
EINECS 202-193-9
dibenzo{b,e}pyrazine
Dibenzoparadiazine
azophenylene
9,10-diazaanthracene

吩嗪物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
357.2±15.0 °C at 760 mmHg

[ 熔点 ]:
172-176 °C(lit.)

[ 分子式 ]:
C₁₂H₈N₂

[ 分子量 ]:
180.205

[ 闪点 ]:
160.3±11.7 °C

[ 精确质量 ]:
180.068741

[ PSA ]:
25.78000

[ LogP ]:
2.84

[ 外观性状 ]:
黄色至棕色结晶粉末

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
1.740

[ 储存条件 ]:
室温

[ 水溶解性 ]:
insoluble

吩嗪MSDS

吩嗪毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SG1360000

CHEMICAL NAME :: Phenazine

CAS REGISTRY NUMBER :: 92-82-0

BEILSTEIN REFERENCE NO. :: 0126500

LAST UPDATED :: 199712

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C12-H8-N2

MOLECULAR WEIGHT :: 180.22

WISWESSER LINE NOTATION :: T C666 BN INJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 400 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 180 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Implant

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 7 mg/kg

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Kidney, Ureter, Bladder - tumors

MUTATION DATA

TEST SYSTEM :: Insect - Drosophila melanogaster

DOSE/DURATION :: 9700 nmol/vial

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 369,75,1996

吩嗪安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22;R68

[ 安全声明 (欧洲) ]:
S22-S24/25-S36/37

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
SG1360000

[ 海关编码 ]:
29163900

吩嗪合成路线

吩嗪上下游产品

吩嗪上游产品

吩嗪下游产品

吩嗪制备

可将苯胺蒸气通过红热管，或将邻苯二胺和邻苯二酚在管道中加热，或将2-氨基二苯胺和一氧化铅蒸馏而制得。

吩嗪海关

[ 海关编码 ]: 2933990090

[ 中文概述 ]:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

吩嗪文献

Extraction optimization, characterization and antioxidant activity in vitro of polysaccharides from mulberry (Morus alba L.) leaves.

Carbohydr. Polym. 128 , 52-62, (2015)

Extraction optimization, characterization and antioxidant activity in vitro of polysaccharides from mulberry leaves (MLP) were investigated in the present study. The optimal extraction conditions with...

Resveratrol loaded gelatin nanoparticles synergistically inhibits cell cycle progression and constitutive NF-kappaB activation, and induces apoptosis in non-small cell lung cancer cells.

Biomed. Pharmacother. 70 , 274-82, (2015)

Previously, we reported that the prepared resveratrol (RSV) loaded gelatin nanoparticles (GNPs) possessed enhanced anticancer effect than free RSV in non-small cell lung carcinoma cells and Swiss albi...

Chemical constituents and biological activities of Cirsium leucopsis, C. sipyleum, and C. eriophorum.

Z. Naturforsch., C, J. Biosci. 69(9-10) , 381-90, (2015)

Two endemic Cirsium species, C. leucopsis DC. and C. sipyleum O. Schwarz, and C. eriophorum (L.) Scop. growing in Turkey were investigated to establish their secondary metabolites, fatty acid composit...

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吩嗪