3425-61-4

• 常用中文名：特戊基过氧化氢
• 常用英文名：tert-Amyl hydroperoxide
• CAS号：3425-61-4
• 分子式：C₅H₁₂O₂
• 分子量：104.14800
• 发布时间：2018-07-29 14:38:15
• 更新时间：2024-01-06 07:44:09

名称

• 中文名: 特戊基过氧化氢
• 英文名: 2-hydroperoxy-2-methylbutane
• 中文别名: 1,1-二甲丙基过氧化氢
• 英文别名: Trigonox TAHP; 1,1-Dimethylpropyl hydroperoxide; t-Amyl hydroperoxide; tert-Amylhydroperoxide; tertiary amyl hydroperoxide; 2-methylbutane hydroperoxide; 1,1-dimethyl-propylhydroperoxid; Hydroperoxide,1,1-dimethylpropyl; tert-pentyl hydroperoxide

物化性质

• 密度: 0.905 g/cm3
• 沸点: 144.6ºC
• 分子式: C₅H₁₂O₂
• 分子量: 104.14800
• 精确质量: 104.08400
• PSA: 29.46000
• LogP: 1.66460
• 折射率: 1.409

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : SC3067000 CHEMICAL NAME : tert-Pentyl hydroperoxide CAS REGISTRY NUMBER : 3425-61-4 BEILSTEIN REFERENCE NO. : 1731878 LAST UPDATED : 199712 DATA ITEMS CITED : 8 MOLECULAR FORMULA : C5-H12-O2 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 864 mg/kg TOXIC EFFECTS : Behavioral - general anesthetic Kidney, Ureter, Bladder - hematuria Blood - methemoglobinemia-carboxyhemoglobin REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 22(7),51,1978 TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1510 mg/m3 TOXIC EFFECTS : Lungs, Thorax, or Respiration - changes in lung weight Blood - methemoglobinemia-carboxyhemoglobin Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - cytochrome oxidases (including oxidative phosphorylation) REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(5),53,1981 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 225 mg/kg TOXIC EFFECTS : Behavioral - general anesthetic Kidney, Ureter, Bladder - hematuria Blood - methemoglobinemia-carboxyhemoglobin REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 22(7),51,1978 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 450 mg/kg TOXIC EFFECTS : Lungs, Thorax, or Respiration - changes in lung weight Blood - methemoglobinemia-carboxyhemoglobin Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - cytochrome oxidases (including oxidative phosphorylation) REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(5),53,1981 TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1370 mg/m3 TOXIC EFFECTS : Lungs, Thorax, or Respiration - changes in lung weight Blood - methemoglobinemia-carboxyhemoglobin Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - cytochrome oxidases (including oxidative phosphorylation) REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(5),53,1981 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 275 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,21,1982 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 5 mg/m3;Skin JAN 1993

安全

• 海关编码: 2909600000

合成路线

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海关

海关编码	2909600000
中文概述	2909600000 过氧化醇、过氧化醚、过氧化酮及其卤化、磺化、硝化、亚硝化衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2909600000 alcohol peroxides, ether peroxides, ketone peroxides and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%