1106696-25-6

• 常用中文名：三叔丁基磷三氟甲磺酸酯
• 常用英文名：Tri-t-butylphosphonium trifluoromethanesulfonate, 99 Stabiphos T
• CAS号：1106696-25-6
• 分子式：C₁₃H₂₈F₃O₃PS
• 分子量：352.39400
• 发布时间：2016-06-13 00:17:13
• 更新时间：2024-04-03 11:11:43

名称

• 中文名: 三叔丁基磷三氟甲磺酸酯
• 英文名: Tri-t-butylphosphonium trifluoromethanesulfonate, 99% Stabiphos T
• 英文别名: 2-Cyclohexyl-2-methylbutane; p-t-Amyl cyclohexane; PtBu3*F3CSO3H; cis-4-tert-amylcyclohexane; tert-Pentyl-cyclohexan; 4-t-pentylcyclohexane; 2-Methyl-2-cyclohexylbutane; tert-AMYLCYCLOHEXANE; tert-Pentylcyclohexane; Cyclohexane,tert-pentyl; tri-tert-butylphosphonium trifluoromethanesulfonate

物化性质

• 分子式: C₁₃H₂₈F₃O₃PS
• 分子量: 352.39400
• 精确质量: 352.14500
• PSA: 76.34000
• LogP: 6.33860

MSDS

Section 1: Product Identification Chemical Name:Tri-t-butylphosphonium trifluoromethanesulfonate, 99% Stabiphos T CAS Registry Number:1106696-25-6 Formula:[(C4H9)3PH]+CF3SO3- EINECS Number:none Chemical Family:organophosphine salt Synonym:Stabiphos T Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound1106696-25-6100%2.5 mg/m3 (as F)2.5 mg/m3 (as F) Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Product contains fluorine which under certain conditions of use, decomposition, or metabolism, may generate Chronic Health Affects:fluoride ion, causing, nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth structure, kidney and liver damage. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, dry powder or foam If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a tightly sealed container. Keep in a cool, dry, well-ventilated place. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white solid Molecular Weight:352.4 Melting Point:175° Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:strong oxidizing agents Decomposition Products:carbon monoxide, hydrogen fluoride, sulfur oxides and phosphorus oxides SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

合成路线

13716-12-6 1493-13-6 ~73% 1106696-25-6

文献：Dynamit Nobel GmbH Explosivstoff- und Systemtechnik Patent: EP2019107 A1, 2009 ; Location in patent: Page/Page column 8-9 ;

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