10262-65-4

• 常用中文名：2-(2-溴乙酰基)-6-甲氧基萘
• 常用英文名：2-Bromoacetyl-6-methoxynaphtalene
• CAS号：10262-65-4
• 分子式：C₁₃H₁₁BrO₂
• 分子量：279.12900
• 发布时间：2018-08-19 12:08:13
• 更新时间：2024-01-12 20:55:49
• 磁性金属配合物

名称

• 中文名: 2-(溴乙酰基)-6-甲氧基萘
• 英文名: 2-bromo-1-(6-methoxynaphthalen-2-yl)ethanone
• 中文别名: 2-(2-溴乙酰基)-6-甲氧基萘
• 英文别名: 6-methoxy-2-(bromoacetyl)naphthalene; Ethanone,2-bromo-1-(6-methoxy-2-naphthalenyl); 2-bromo-1-(6-methoxy-[2]naphthyl)-ethanone; 2-Bromoacetyl-6-methoxynaphtalene; 2-Bromo-6'-methoxy-2'-acetonaphthone; 2-bromo-6'-methoxy-2'-acetonaphthone; 2-(3-ETHOXYPHENOXY)ANILINE; 2-(BroMoacetyl)-6-Methoxynaphthalene; 2-(Bromoacetyl)-6-methoxynaphthalene; 2-bromo-1-(2-methoxynaphthalen-6-yl)ethanone

物化性质

• 密度: 1.451 g/cm3
• 沸点: 387.2ºCat 760 mmHg
• 分子式: C₁₃H₁₁BrO₂
• 分子量: 279.12900
• 闪点: 188ºC
• 精确质量: 277.99400
• PSA: 26.30000
• LogP: 3.42600
• 蒸汽压: 3.35E-06mmHg at 25°C
• 折射率: 1.631
• 储存条件: 室温，干燥
• 分子结构:

  1、 摩尔折射率：68.53

  2、 摩尔体积（cm³/mol）：192.2

  3、 等张比容（90.2K）：505.0

  4、 表面张力（dyne/cm）：47.6

  5、 极化率（10-24cm3）：27.16

• 计算化学:

  1.疏水参数计算参考值（XlogP）:3.6

  2.氢键供体数量:0

  3.氢键受体数量:2

  4.可旋转化学键数量:3

  5.互变异构体数量:2

  6.拓扑分子极性表面积26.3

  7.重原子数量:16

  8.表面电荷:0

  9.复杂度:254

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

MSDS

2-(Bromoacetyl)-6-methoxynaphthalene Revision number: 1 SAFETY DATA SHEET Section1. BASE INFORMATION Product name:2-(Bromoacetyl)-6-methoxynaphthalene Revision number:1 Section2. HAZARDS IDENTIFICATION Classification of the GHS PHYSICAL HAZARDS Corrosive to metalsCategory 1 HEALTH HAZARDS Skin corrosion/irritationCategory 1B Category 1 Serious eye damage/eye irritation ENVIRONMENTAL HAZARDSNot classified GHS label elements Pictograms or hazard symbols Signal wordDanger Hazard statementMay be corrosive to metals Causes severe skin burns and eye damage Precautionary statements Keep only in original container. [Prevention] Do not breathe. Wash hands thoroughly after handling. Wear protective gloves/eye protection/face protection. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for [Response] breathing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or doctor/physician. Absorb spillage to prevent material damage. [Storage]Store locked up. [Disposal]Dispose of contents/container through a waste management company authorized by the local government Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Substance/mixture: 2-(Bromoacetyl)-6-methoxynaphthalene Section3. COMPOSITION/INFORMATION ON INGREDIENTS Component(s):2-(Bromoacetyl)-6-methoxynaphthalene Percent:>98.0%(GC) CAS Number:10262-65-4 Synonyms:2-Bromo-6'-methoxy-2'-acetonaphthone Chemical Formula:C13H11BrO2 Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. Immediately call a POISON CENTER or doctor/physician. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician. Ingestion:Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air- tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water spray, carbon dioxide. media: Specific hazards:Take care as it may decompose upon combustion or in high temperatures to generate poisonous fume. Specific methods:Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Use extra personal protective equipment (P3 filter respirator for toxic particles). Keep Personal precautions, protective equipment and people away from and upwind of spill/leak. Entry to non-involved personnel should emergency procedures: be controlled around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it. containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with up: appropriate laws and regulations. Section7. HANDLING AND STORAGE Handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent dispersion of dust. Wash hands and face thoroughly after handling. Use a closed system if possible. Use a local exhaust if dust or aerosol will be generated. Advice on safe handling:Avoid contact with skin, eyes and clothing. Use corrosive resistant equipment. Storage Storage conditions:Keep container tightly closed. Store in a cool and dark place. Store locked up. Store away from incompatible materials such as oxidizing agents. Packaging material:Law is followed. Keep only in original container. 2-(Bromoacetyl)-6-methoxynaphthalene Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls:Install a closed system or local exhaust. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Dust respirator, self-contained breathing apparatus(SCBA), supplied air respirator, etc. Use respirators approved under appropriate government standards and follow local and national regulations. Impervious gloves. Hand protection: Eye protection:Safety goggles. A face-shield, if the situation requires. Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Solid Form:crystal - powder White - Pale yellow Color: Odor:No data available pH: No data available Melting point/freezing point:112 °C Boiling Point/Range:No data available Flash Point:No data available Explosive limits Lower:No data available No data available Upper: Density:No data available No data available Solubility: Section10. STABILITY AND REACTIVITY Stability:Stable under proper conditions. Reactivity:No special reactivity has been reported. Incompartible materials: oxidizing agents, strong bases Hazardous Decomposition Carbon monoxide, Carbon dioxide, Hydrogen bromide Products: Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC =No data available No data available NTP = Reproductive toxicity:No data available Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available Crustacea:No data available Algae:No data available Persistence / degradability: No data available BioaccumulativeNo data available potential(BCF): Mobillity in soil log Pow:No data available Soil adsorption (Koc):No data available Henry's LawNo data available constant(PaM3/mol): 2-(Bromoacetyl)-6-methoxynaphthalene Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:8: Corrosive. UN-No:3261 Proper shipping name:Corrosive solid, acidic, organic, n.o.s. II Packing group: Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 海关编码: 2914700090

合成路线

3900-45-6 ~95% 10262-65-4

文献：Su, Qiong; Zhao, Zi-Jian; Xu, Feng; Lou, Peng-Cai; Zhang, Kai; Xie, De-Xun; Shi, Lei; Cai, Qing-Yun; Peng, Zhi-Hong; An, De-Lie European Journal of Organic Chemistry, 2013 , # 8 p. 1551 - 1557

3900-45-6 ~50% 10262-65-4 52997-56-5

文献：Phosphorus and Sulfur and the Related Elements, , vol. 25, p. 357 - 368

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海关

海关编码	2914700090
中文概述	2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 丙酮报明包装
Summary	HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%