13465-15-1

• 常用中文名：高氯酸铟(III)八水合物
• 常用英文名：indium perchlorate
• CAS号：13465-15-1
• 分子式：Cl₃H₁₆InO₂₀
• 分子量：557.29200
• 相关类别： 无机化工 无机盐 金属卤化物及卤酸盐 金属氯化物及盐
• 发布时间：2018-05-21 08:00:00
• 更新时间：2024-01-19 09:27:01

名称

• 中文名: 八水高氯酸铟
• 英文名: indium perchlorate
• 中文别名: 八水合高氯酸铟
• 英文别名: Indiumperchlorateoctahydratewhitextl; INDIUM(III) PERCHLORATE; Indium(III) perchlorate octahydrate (metals basis); EINECS 236-874-7; Indium(III) perchlorate octahydrate; Indium (III) perchlorate octahydrate (-In); MFCD00150241

物化性质

• 沸点: 200ºC
• 熔点: 80°C
• 分子式: Cl₃H₁₆InO₂₀
• 分子量: 557.29200
• 精确质量: 555.83400
• PSA: 296.65000
• LogP: 0.12850
• 外观性状: crystal | white
• 储存条件:

  常温密闭，阴凉通风干燥

• 稳定性:

  常温常压下稳定

  避免的物料 还原剂 易氧化材料 有机材料.易溶于水、乙醇。

• 水溶解性: It is soluble in water.
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：555.833929 Da

  8、标称质量：556 Da

  9、平均质量：557.292 Da

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:12

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积223

  7.重原子数量:16

  8.表面电荷:0

  9.复杂度:95.8

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:4

• 更多:

  1. 性状：无色无味晶体

  2. 密度（g/mL,25/4℃）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：-80

  5. 沸点（ºC,常压）：200

  6. 沸点（ºC,5.2kPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：不适用的

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：可溶解的

MSDS

Section 1: Product Identification Chemical Name:Indium (III) perchlorate octahydrate (99.9%-In) CAS Registry Number:13465-15-1 Formula:In(ClO4)3.8H2O EINECS Number:none Chemical Family:metal perchlorate salt Synonym:Perchloric acid, Indium(III) salt, octahydrate Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound13465-15-1100%0.1mg/m3no data Section 3: Hazards Identification Emergency Overview:Irritating to eyes, skin and respiratory tract. May be harmful if swallowed. Primary Routes of Exposure:Ingestion Eye Contact:Causes moderate irritation of the eyes. Skin Contact:Causes moderate irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. No specific information is available on the physiological effects of ingestion. May cause gastrointestinal Ingestion: irritation, nausea, and vomiting. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:Perchlorates reversibly inhibit thyroid iodine uptake. Kidney function may be affected. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:Water spray Spray closed containers with water until fire is out. Avoid contact with combustible material. Fire fighters Special Fire Fighting Procedures: should be equipped with a NIOSH approved self-contained breathing apparatus. Hazardous Combustion andIf involved in a fire this material may emit corrosive hydrogen chloride fumes. Decomposion Products: Releases oxygen on heating. May decompose explosively under fire fighting conditions. Do not mix with Unusual Fire or Explosion Hazards: combustibles. SECTION 6: Accidental Release Measures Do not mix spilled powder with any combustible materials, such as sawdust. Sweep up the solid and dilute Spill and Leak Procedures: with water. SECTION 7: Handling and Storage Handling and Storage:Store in a tightly sealed container in a cool dry place away from combustible and flammable materials. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white xtl. Molecular Weight:413.17 (557.26) Melting Point:~80° Boiling Point:200°C dec. Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:very soluble SECTION 10: Stability and Reactivity Stability:Air and moisture stable solid Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:Any contact with combustible matter. Incompatibility:Reducing agents, organic matter, active metals, phosphorus, sulfur, hydrazine, hydroxylamine, strong acids Decomposition Products:Oxygen, Indium oxide, hydrogen chloride, SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No data available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Perchlorates, Inorganic, N.O.S. Hazard Class (CFR):5.1 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 1481 Shipping Name (IATA):Perchlorates, Inorganic, N.O.S. Hazard Class (IATA):5.1 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 1481 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 1、急性毒性：主要的刺激性影响： 在皮肤上面：刺激皮肤和粘膜； 在眼睛上面：刺激的影响；没有已知的敏化影响。 生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

安全

• 危险品运输编码: UN1481
• 包装等级: II
• 危险类别: 5.1

制备

使纯金属铟或三水合三氯化铟与过量的70％高氯酸反应。所得溶液浓缩至有高氯酸蒸气产生。冷却，过滤。所得结晶在以H2SO4为干燥剂的真空干燥器中干燥。