14768-11-7

14768-11-7结构式

常用中文名：FERROCYPHEN
常用英文名：FERROCYPHEN
CAS号：14768-11-7
分子式：C₂₆H₁₆FeN₆
分子量：468.29000
发布时间：2017-02-19 04:28:08
更新时间：2024-01-13 17:11:05

英文名	iron(2+),1,10-phenanthroline,dicyanide
英文别名	[Fe(1,10-phenanthroline)2(CN)2] EINECS 238-833-9 Fe(phen)2(CN)2 Bis(cyano-C)bis(1,10-phenanthroline-N1,N10)iron Dicyano-bis(1,10-phenanthrolin)eisen II iron(2+) cyanide 1,10-phenanthroline(1:2:2) FeII(1,10-phenanthroline)2(CN)2 dicyanobis(1,10-phenanthroline)iron(II) Bis(o-phenanthroline)iron(II) cyanide trihydrate

沸点	365.1ºC at 760 mmHg
分子式	C₂₆H₁₆FeN₆
分子量	468.29000
闪点	164.8ºC
精确质量	468.07900
PSA	99.14000
LogP	5.59706
蒸汽压	3.38E-05mmHg at 25°C

Name:	Dicyanobis(1 10-Phenanthroline) Iron Trihydrate 99% (Titr.) Material Safety Data Sheet
Synonym:	None
CAS:	14768-11-7

Section 1 - Chemical Product MSDS Name:Dicyanobis(1 10-Phenanthroline) Iron Trihydrate 99% (Titr.) Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
14768-11-7	Iron,bis(cyano-c)bis(1,10-phenanthroli	99	238-833-9

Hazard Symbols: XN
Risk Phrases: 20/21/22

Section 3 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 14768-11-7: Belgium - TWA: (listed as iron salts (soluble)): 1 mg/m3 VLE (as Malaysia: (listed as iron salts (soluble)): 1 mg/m3 TWA (as Fe) Netherlands: (listed as iron salts (soluble)): 1 mg/m3 MAC (as Fe Spain: (listed as iron salts (soluble)): 1 mg/m3 VLA-ED (as Fe) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C26H16FeN6.3H2O
Molecular Weight: 522.34

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen cyanide, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 14768-11-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Iron,bis(cyano-c)bis(1,10-phenanthroline-n1,n10)- - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 14768-11-7: No information available.
Canada
CAS# 14768-11-7 is listed on Canada's NDSL List.
CAS# 14768-11-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14768-11-7 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

危险品运输编码	UN 2811
包装等级	II
危险类别	6.1(a)

14634-91-4

~90%

14768-11-7

文献：Rollick, K. L.; Kochi, J. K. Organometallics, 1982 , vol. 1, p. 725 - 732

66-71-7

7439-89-6

14768-11-7

文献：Griffiths, Lynne; Straughan, Brian P.; Gardiner, Derek J. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1983 , p. 305 - 310

47836-89-5

57-12-5

14768-11-7

文献：Blandamer, Michael J.; Burgess, John; Clark, Barbara Journal of the Chemical Society, Chemical Communications, 1983 , # 12 p. 659 - 660

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