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9003-28-5

9003-28-5结构式
9003-28-5结构式
  • 常用中文名:聚丁烯
  • 常用英文名:poly(1-butene)
  • CAS号:9003-28-5
  • 分子式:C4H8
  • 分子量:56.10630
  • 相关类别: 食品添加剂 胶姆糖基础剂
  • 发布时间:2018-03-17 08:00:00
  • 更新时间:2024-01-02 11:46:53
  • 1.可作为胶黏剂和密封剂配方中的基础聚合物或助剂;也可用于无定形聚α-烯烃、烯烃聚合物和共聚物、乙烯丙烯二聚单体,以及弹性体为基础的聚合物的改性。其中,Montell PB-1聚合物是理想的包装、运输、建筑和非刚性粘接的胶黏剂和密封剂。

    2.由于聚丁烯具有长的放置时间、配方的可变性、高的附着力和黏合强度、宽的使用温度并可与增塑树脂配合使用等优点,可作为胶黏剂和密封剂配方中的基础聚合物或助剂;也可用于无定形聚α烯烃、烯烃聚合物和共聚物、乙烯丙烯二聚单体,以及弹性体为基础的聚合物的改性。其中,Montell PB-1聚合物是理想的包装、运输、建筑和非刚性粘接的胶黏剂和密封剂。


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中文名 聚丁烯 PB
英文名 poly(ethylethylene)
中文别名 聚丁烯
英文别名 MFCD00084367
1-Butene
密度 0.625 g/cm3
熔点 85 - 130ºC (varies with molecular weight)
分子式 C4H8
分子量 56.10630
精确质量 56.06260
LogP 1.58240
外观性状 白色或色的发黏的固体
储存条件 密闭,阴凉干燥处保存,确保有良好的通风 远离火种、热源。
稳定性

如果遵照规格使用和储存则不会分解,未有已知危险发生

避免强氧化剂

具有刚性人固体,是1-丁烯单体的等规立构高分子均聚物。该材料与其他聚烯烃比较,具有较高的抗张强度、好的耐热性、抗化学腐蚀性、优良的抗蠕变性。在油、洗涤剂和其他溶剂中,不会产生脆化,只有在98%浓硫酸、发烟硝酸、液体溴等强氧化剂的作用下,才会产生应力开裂。具有与超高分子量聚乙烯媲美的非常好的耐磨性,并可容纳大量的填料。

通常在93℃以下,聚1-丁烯可以耐酸、耐碱等各种化学药品,在温度高于60℃时,未加颜料的树脂溶于芳烃和氯代烃溶剂。此外,聚1-丁烯还具有良好的隔湿性,其气体和水蒸气透过率稍低于低密度聚乙烯。聚1-丁烯的电绝缘性能也较好。聚1-丁烯最突出的性能提具有优良的耐蠕变性能,并具有良好的耐环境应力开裂性。在长期的耐环境应力开裂试验中,当其他聚烯烃发生应力开裂时,聚1-丁烯仍不开裂。聚1-丁烯耐热性好,可在-30-100℃范围内长期使用,而聚丙烯在高温度下使用就会变脆。

计算化学

1、 疏水参数计算参考值(XlogP):

2、 氢键供体数量:0

3、 氢键受体数量:0

4、 可旋转化学键数量:1

5、 互变异构体数量:

6、 拓扑分子极性表面积(TPSA):0

7、 重原子数量:8

8、 表面电荷:0

9、 复杂度:29.2

10、 同位素原子数量:0

11、 确定原子立构中心数量:0

12、 不确定原子立构中心数量:0

13、 确定化学键立构中心数量:1

14、 不确定化学键立构中心数量:0

15、 共价键单元数量:2

更多

1. 性状:片状

2. 密度(g/mLat 25°C):0.91

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):未确定

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,0.1mmHg):未确定

7. 折射率(n20/D):未确定

8. 闪点(ºC):未确定

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):未确定

11. 蒸气压(mmHg,37ºC):未确定

12. 饱和蒸气压(kPa,114.4 ºC):未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(MPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:未确定

Name: Poly(1-Butene) Isotactic Average MW ca. 185000 (GPC) Material Safety Data Sheet
Synonym: None
CAS: 9003-28-5
Section 1 - Chemical Product MSDS Name:Poly(1-Butene) Isotactic Average MW ca. 185000 (GPC) Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
9003-28-5 Poly(1-Butene) ca 100 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 9003-28-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Pellets
Color: transparent
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 125 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9100
Molecular Formula: [-CH2CH(C2H5)-]n
Molecular Weight:

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 9003-28-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Poly(1-Butene) - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 9003-28-5: No information available.
Canada
CAS# 9003-28-5 is listed on Canada's DSL List.
CAS# 9003-28-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 9003-28-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
WGK德国 3

聚1-丁烯系由高纯度1-丁烯在立体定向齐格勒-纳塔催化剂作用下聚合而成。其制备过程大致为:把经过脱水、脱氧的1-丁烯通入预先装有四氯化钛/三乙基铝[Al/Ti=1:1(摩尔比)]络合催化剂和乙烷溶剂的反应釜中,在室温和常压[或150℃和6.08Mpa(60atm)]的条件下进行聚合反应。在反应过程中不时地加入乙烷以稀释之,至反应终点出料,然后用乙醇使聚合产物中的催化剂失去活性,并洗涤,除净催化剂,即得具有等规结构、高结晶度的聚1-丁烯。目前已知它有5种晶型,从挤出机出来的熔融聚合物结晶时,生成亚稳定的晶型II,在室温和常压下放置5-10天陈化后,晶型II就会不可逆地转变稳定的晶型I。

近年来,芬兰Neste公司开发了一种低能耗的聚1-丁烯生产新工艺。聚合反应采用高活性齐格勒-纳塔配位聚合催化剂,简化了工艺流程,去掉了分离催化剂残渣和无规聚合物等工序。整个工艺流程只包括聚合、干燥和造粒三个步骤。在聚合反应中,可直生成高熔点、结晶形态稳定的晶型I聚合物。

9003-28-5 preparation