9003-28-5

• 常用中文名：聚丁烯
• 常用英文名：poly(1-butene)
• CAS号：9003-28-5
• 分子式：C₄H₈
• 分子量：56.10630
• 相关类别： 食品添加剂 胶姆糖基础剂
• 发布时间：2018-03-17 08:00:00
• 更新时间：2024-01-02 11:46:53

• 1.可作为胶黏剂和密封剂配方中的基础聚合物或助剂；也可用于无定形聚α-烯烃、烯烃聚合物和共聚物、乙烯丙烯二聚单体，以及弹性体为基础的聚合物的改性。其中，Montell PB-1聚合物是理想的包装、运输、建筑和非刚性粘接的胶黏剂和密封剂。

  2.由于聚丁烯具有长的放置时间、配方的可变性、高的附着力和黏合强度、宽的使用温度并可与增塑树脂配合使用等优点，可作为胶黏剂和密封剂配方中的基础聚合物或助剂；也可用于无定形聚α烯烃、烯烃聚合物和共聚物、乙烯丙烯二聚单体，以及弹性体为基础的聚合物的改性。其中，Montell PB-1聚合物是理想的包装、运输、建筑和非刚性粘接的胶黏剂和密封剂。

名称

• 中文名: 聚丁烯 PB
• 英文名: poly(ethylethylene)
• 中文别名: 聚丁烯
• 英文别名: MFCD00084367; 1-Butene

物化性质

• 密度: 0.625 g/cm3
• 熔点: 85 - 130ºC (varies with molecular weight)
• 分子式: C₄H₈
• 分子量: 56.10630
• 精确质量: 56.06260
• LogP: 1.58240
• 外观性状: 白色或色的发黏的固体
• 储存条件: 密闭,阴凉干燥处保存，确保有良好的通风 远离火种、热源。
• 稳定性:

  如果遵照规格使用和储存则不会分解，未有已知危险发生

  避免强氧化剂

  具有刚性人固体，是1-丁烯单体的等规立构高分子均聚物。该材料与其他聚烯烃比较，具有较高的抗张强度、好的耐热性、抗化学腐蚀性、优良的抗蠕变性。在油、洗涤剂和其他溶剂中，不会产生脆化，只有在98%浓硫酸、发烟硝酸、液体溴等强氧化剂的作用下，才会产生应力开裂。具有与超高分子量聚乙烯媲美的非常好的耐磨性，并可容纳大量的填料。

  通常在93℃以下，聚1-丁烯可以耐酸、耐碱等各种化学药品，在温度高于60℃时，未加颜料的树脂溶于芳烃和氯代烃溶剂。此外，聚1-丁烯还具有良好的隔湿性，其气体和水蒸气透过率稍低于低密度聚乙烯。聚1-丁烯的电绝缘性能也较好。聚1-丁烯最突出的性能提具有优良的耐蠕变性能，并具有良好的耐环境应力开裂性。在长期的耐环境应力开裂试验中，当其他聚烯烃发生应力开裂时，聚1-丁烯仍不开裂。聚1-丁烯耐热性好，可在-30-100℃范围内长期使用，而聚丙烯在高温度下使用就会变脆。

• 计算化学:

  1、 疏水参数计算参考值（XlogP）：

  2、 氢键供体数量：0

  3、 氢键受体数量：0

  4、 可旋转化学键数量：1

  5、 互变异构体数量：

  6、 拓扑分子极性表面积（TPSA）：0

  7、 重原子数量：8

  8、 表面电荷：0

  9、 复杂度：29.2

  10、 同位素原子数量：0

  11、 确定原子立构中心数量：0

  12、 不确定原子立构中心数量：0

  13、 确定化学键立构中心数量：1

  14、 不确定化学键立构中心数量：0

  15、 共价键单元数量：2

• 更多:

  1. 性状：片状

  2. 密度（g/mLat 25°C）：0.91

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,0.1mmHg）：未确定

  7. 折射率（n20/D）：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（mmHg,37ºC）：未确定

  12. 饱和蒸气压（kPa,114.4 ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（MPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Name: Poly(1-Butene) Isotactic Average MW ca. 185000 (GPC) Material Safety Data Sheet Synonym: None CAS: 9003-28-5 Section 1 - Chemical Product MSDS Name:Poly(1-Butene) Isotactic Average MW ca. 185000 (GPC) Material Safety Data Sheet Synonym:None Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 9003-28-5 Poly(1-Butene) ca 100 unlisted Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 9003-28-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Pellets Color: transparent Odor: odorless pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 125 deg C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: .9100 Molecular Formula: [-CH2CH(C2H5)-]n Molecular Weight: Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, dust generation, excess heat. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 9003-28-5 unlisted. LD50/LC50: Not available. Carcinogenicity: Poly(1-Butene) - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 9003-28-5: No information available. Canada CAS# 9003-28-5 is listed on Canada's DSL List. CAS# 9003-28-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 9003-28-5 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• WGK德国: 3

制备

聚1-丁烯系由高纯度1-丁烯在立体定向齐格勒-纳塔催化剂作用下聚合而成。其制备过程大致为：把经过脱水、脱氧的1-丁烯通入预先装有四氯化钛/三乙基铝[Al/Ti=1:1(摩尔比)]络合催化剂和乙烷溶剂的反应釜中，在室温和常压[或150℃和6.08Mpa（60atm）]的条件下进行聚合反应。在反应过程中不时地加入乙烷以稀释之，至反应终点出料，然后用乙醇使聚合产物中的催化剂失去活性，并洗涤，除净催化剂，即得具有等规结构、高结晶度的聚1-丁烯。目前已知它有5种晶型，从挤出机出来的熔融聚合物结晶时，生成亚稳定的晶型II，在室温和常压下放置5-10天陈化后，晶型II就会不可逆地转变稳定的晶型I。

近年来，芬兰Neste公司开发了一种低能耗的聚1-丁烯生产新工艺。聚合反应采用高活性齐格勒-纳塔配位聚合催化剂，简化了工艺流程，去掉了分离催化剂残渣和无规聚合物等工序。整个工艺流程只包括聚合、干燥和造粒三个步骤。在聚合反应中，可直生成高熔点、结晶形态稳定的晶型I聚合物。