中文名 | 聚丁烯 PB |
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英文名 | poly(ethylethylene) |
中文别名 | 聚丁烯 |
英文别名 |
MFCD00084367
1-Butene |
密度 | 0.625 g/cm3 |
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熔点 | 85 - 130ºC (varies with molecular weight) |
分子式 | C4H8 |
分子量 | 56.10630 |
精确质量 | 56.06260 |
LogP | 1.58240 |
外观性状 | 白色或色的发黏的固体 |
储存条件 | 密闭,阴凉干燥处保存,确保有良好的通风 远离火种、热源。 |
稳定性 | 如果遵照规格使用和储存则不会分解,未有已知危险发生 避免强氧化剂具有刚性人固体,是1-丁烯单体的等规立构高分子均聚物。该材料与其他聚烯烃比较,具有较高的抗张强度、好的耐热性、抗化学腐蚀性、优良的抗蠕变性。在油、洗涤剂和其他溶剂中,不会产生脆化,只有在98%浓硫酸、发烟硝酸、液体溴等强氧化剂的作用下,才会产生应力开裂。具有与超高分子量聚乙烯媲美的非常好的耐磨性,并可容纳大量的填料。 通常在93℃以下,聚1-丁烯可以耐酸、耐碱等各种化学药品,在温度高于60℃时,未加颜料的树脂溶于芳烃和氯代烃溶剂。此外,聚1-丁烯还具有良好的隔湿性,其气体和水蒸气透过率稍低于低密度聚乙烯。聚1-丁烯的电绝缘性能也较好。聚1-丁烯最突出的性能提具有优良的耐蠕变性能,并具有良好的耐环境应力开裂性。在长期的耐环境应力开裂试验中,当其他聚烯烃发生应力开裂时,聚1-丁烯仍不开裂。聚1-丁烯耐热性好,可在-30-100℃范围内长期使用,而聚丙烯在高温度下使用就会变脆。 |
计算化学 | 1、 疏水参数计算参考值(XlogP): 2、 氢键供体数量:0 3、 氢键受体数量:0 4、 可旋转化学键数量:1 5、 互变异构体数量: 6、 拓扑分子极性表面积(TPSA):0 7、 重原子数量:8 8、 表面电荷:0 9、 复杂度:29.2 10、 同位素原子数量:0 11、 确定原子立构中心数量:0 12、 不确定原子立构中心数量:0 13、 确定化学键立构中心数量:1 14、 不确定化学键立构中心数量:0 15、 共价键单元数量:2 |
更多 | 1. 性状:片状 2. 密度(g/mLat 25°C):0.91 3. 相对蒸汽密度(g/mL,空气=1):未确定 4. 熔点(ºC):未确定 5. 沸点(ºC,常压):未确定 6. 沸点(ºC,0.1mmHg):未确定 7. 折射率(n20/D):未确定 8. 闪点(ºC):未确定 9. 比旋光度(º):未确定 10. 自燃点或引燃温度(ºC):未确定 11. 蒸气压(mmHg,37ºC):未确定 12. 饱和蒸气压(kPa,114.4 ºC):未确定 13. 燃烧热(KJ/mol):未确定 14. 临界温度(ºC):未确定 15. 临界压力(MPa):未确定 16. 油水(辛醇/水)分配系数的对数值:未确定 17. 爆炸上限(%,V/V):未确定 18. 爆炸下限(%,V/V):未确定 19. 溶解性:未确定 |
Synonym:None Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 9003-28-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Pellets Color: transparent Odor: odorless pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 125 deg C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: .9100 Molecular Formula: [-CH2CH(C2H5)-]n Molecular Weight: Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, dust generation, excess heat. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 9003-28-5 unlisted. LD50/LC50: Not available. Carcinogenicity: Poly(1-Butene) - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 9003-28-5: No information available. Canada CAS# 9003-28-5 is listed on Canada's DSL List. CAS# 9003-28-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 9003-28-5 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
WGK德国 | 3 |
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