210842-74-3

• 常用中文名：(S,S)-(-)-2,2'-双[-(N,N-二甲胺基)(苯基)甲基]-1,1'-双(二苯基磷)二茂铁
• 常用英文名：(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
• CAS号：210842-74-3
• 分子式：C₅₂H₅₀FeN₂P₂
• 分子量：820.75900
• 相关类别： 化学试剂 有机试剂 膦配体
• 发布时间：2018-10-12 20:21:45
• 更新时间：2024-01-05 22:32:22

名称

• 中文名: (S,S)-(-)-2,2'-双[-(N,N-二甲胺基)(苯基)甲基]-1,1'-双(二苯基磷)二茂铁
• 英文名: (S,S)-(-)-2,2'-Bis[(R)-(N,N-diMethylaMino)(phenyl)Methyl]-1,1'-bis(diphenylphosphino)ferrocene
• 中文别名: (AlphaR,AlphaR)-2,2-双(Alpha-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁
• 英文别名: (αR,αR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis(diphenylphosphino)ferrocene; 1-[(S)-(Dimethylamino)(phenyl)methyl]-2-(diphenylphosphino)-1,2,3,4,5-cyclopentanepentayl - iron (2:1); 1,2,3,4,5-Cyclopentanepentayl, 1-[(S)-(dimethylamino)phenylmethyl]-2-(diphenylphosphino)-, iron salt (2:1)

物化性质

• 分子式: C₅₂H₅₀FeN₂P₂
• 分子量: 820.75900
• 精确质量: 820.28000
• PSA: 33.66000
• LogP: 9.73510
• 储存条件: 室温，保存在惰性气体中

MSDS

Section 1: Product Identification Chemical Name:(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97% CAS Registry Number:210842-74-3 Formula:C52H50FeN2P2 EINECS Number:None Chemical Family:organophosphine ligand Synonym:none Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound210842-74-3100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and mucous membranes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, eyes Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information available on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards Chronic Health Affects: may be present. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Keep material in a tightly sealed container. Prolonged exposure to the air may result in degradation of the Handling and Storage: product. Handle and store material under an inert atmosphere of nitrogen or argon. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:orange-red solid Molecular Weight:820.76 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:Insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:exposure to oxygen, contact with strong oxidizing agents Incompatibility:Oxidizing agents and halogens Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, phosphorus oxides, nitrogen oxides and iron oxide. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 海关编码: 29319090