24938-91-8

• 常用中文名：十三烷基聚氧乙烯 (18) 醚
• 常用英文名：Polyoxyethylene (18) Tridecyl Ether
• CAS号：24938-91-8
• 分子式：C₁₅H₃₂O₂
• 分子量：244.41300
• 发布时间：2018-10-01 21:51:16
• 更新时间：2024-01-04 11:01:16
• 下载msds

名称

• 中文名: 十三烷基醚聚氧代乙烯
• 英文名: 2-(Tridecyloxy)ethanol
• 英文别名: Phenol,4-(2-phenoxyethyl); MFCD00132049; Polyoxyethylene (18) tridecyl ether

物化性质

• 密度: 0.872g/cm3
• 沸点: >150ºC(lit.)
• 熔点: 28ºC(lit.)
• 分子式: C₁₅H₃₂O₂
• 分子量: 244.41300
• 闪点: >150ºC(lit.)
• 精确质量: 244.24000
• PSA: 29.46000
• LogP: 4.30630
• 外观性状: 透明液体
• 蒸汽压: 3.29E-05mmHg at 25°C
• 折射率: n20/D 1.459(lit.)
• 储存条件:

  密闭，阴凉，通风干燥处

• 稳定性:

  遵照规定使用和储存则不会分解。

  避免氧化剂和强碱

• 分子结构: 1 、 摩尔折射率：不确定 2、 摩尔体积（cm ³/mol）：不确定 3、 等张比容（90.2K）：不确定 4、 表面张力（dyne/cm）：不确定

  5、 极化率：不确定

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:1

  3.氢键受体数量:2

  4.可旋转化学键数量:14

  5.互变异构体数量:无

  6.拓扑分子极性表面积29.5

  7.重原子数量:17

  8.表面电荷:0

  9.复杂度:126

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：液体

  2. 密度（g/mL,25℃）：0.980

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC，常压）不确定

  5. 沸点（ºC,常压）:未确定

  6. 沸点（ºC,1.013hPa）：>150

  7. 折射率（n20/D）：1.532

  8. 闪点（ºC）：>110

  9. 比旋光度（[α]20/D，º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（mmHg,78ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（oC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性(g/l,水，at 20 ºC)：未确定

MSDS

Section 1. Chemical Product and Company Identification Renex 36 Common Name/ Trade Name Renex 36 Section 3. Hazards Identification Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Potential Acute Health Effects CARCINOGENIC EFFECTS: Not available. Potential Chronic Health MUTAGENIC EFFECTS: Not available. Effects TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to liver. Repeated or prolonged exposure to the substance can produce target organs damage. Section 4. First Aid Measures Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least Eye Contact 15 minutes. Get medical attention if irritation occurs. Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Skin Contact Not available. Serious Skin Contact InhalationIf inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Serious InhalationNot available. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an Ingestion unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Not available. Serious Ingestion Section 5. Fire and Explosion Data Flammability of the Product May be combustible at high temperature. Auto-Ignition Temperature Not available. CLOSED CUP: >110°C (230°F). Flash Points Not available. Flammable Limits These products are carbon oxides (CO, CO2). Products of Combustion Fire Hazards in Presence of Slightly flammable to flammable in presence of open flames and sparks, of heat. Various Substances Risks of explosion of the product in presence of mechanical impact: Not available. Explosion Hazards in Risks of explosion of the product in presence of static discharge: Not available. Presence of Various Substances SMALL FIRE: Use DRY chemical powder. Fire Fighting Media LARGE FIRE: Use water spray, fog or foam. Do not use water jet. and Instructions Not available. Special Remarks on Fire Hazards Not available. Special Remarks on Explosion Hazards Renex 36 Section 6. Accidental Release Measures Absorb with an inert material and put the spilled material in an appropriate waste disposal. Small Spill Large SpillAbsorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Section 7. Handling and Storage Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue Precautions under a fume hood. Ground all equipment containing material. Do not breathe gas/fumes/ vapor/spray. Keep away from incompatibles such as oxidizing agents, alkalis. Keep container tightly closed. Keep container in a cool, well-ventilated area. Storage Section 8. Exposure Controls/Personal Protection Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their Engineering Controls respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Personal ProtectionSafety glasses. Synthetic apron. Gloves (impervious). Respiratory protection is not necessary for normal handling. Adequate general (room) ventilation or local exhaust (fume hood) is sufficient. Use a vapor respirator under conditions where exposure to the substance is apparent (e.g. generation of high concentrations of mist or vapor, inadequate ventilation, development of respiratory tract irritation), and engineering controls are not feasible. Be sure to use an approved/certified respirator or equivalent. Personal Protection in Case Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist of a Large SpillBEFORE handling this product. Not available. Exposure Limits Section 9. Physical and Chemical Properties Liquid.Not available. Physical state andO dor appearance Not available. Taste Not available. Molecular Weight Not available. Color Not available. pH (1% soln/water) >150°C (302°F) Boiling Point Not available. Melting Point Not available. Critical Temperature 0.98 (Water = 1) Specific Gravity Not available. Vapor Pressure Not available. Vapor Density Not available. Volatility Not available. Odor Threshold Not available. Water/Oil Dist. Coeff. Not available. Ionicity (in Water) Not available. Dispersion Properties Not available. Solubility Renex 36 Section 10. Stability and Reactivity Data The product is stable. Stability Not available. Instability Temperature Conditions of Instability Excess heat, incompatible materials Incompatibility with various Reactive with oxidizing agents, alkalis. substances Not available. Corrosivity Not available. Special Remarks on Reactivity Not available. Special Remarks on Corrosivity Will not occur. Polymerization Section 11. Toxicological Information Absorbed through skin. Eye contact. Routes of Entry LD50: Not available. Toxicity to Animals LC50: Not available. Chronic Effects on Humans May cause damage to the following organs: liver. Other Toxic Effects onSlightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. Humans Not available. Special Remarks on Toxicity to Animals Not available. Special Remarks on Chronic Effects on Humans Special Remarks on otherAcute Potential Health Effects: Toxic Effects on HumansSkin: May cause skin irritation. Eyes: May cause eye irritation. Inhalation: Inhalation of mist or vapor may cause respiratory tract irritation. Ingestion: Expected to be a low hazard. Chronic Potential Health Effects: Ingestion: Prolonged or repeated ingestion may affect the liver. Section 12. Ecological Information Not available. Ecotoxicity Not available. BOD5 and COD Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation Renex 36 Section 13. Disposal Considerations Waste must be disposed of in accordance with federal, state and local environmental control Waste Disposal regulations. Section 14. Transport Information Not a DOT controlled material (United States). DO T Cl assi fi cati on Not applicable. Identification Not applicable. Special Provisions for Transport DO T (Pi ctograms) Section 15. Other Regulatory Information and Pictograms TSCA 8(b) inventory: Renex 36 Federal and State Regulations California prop. 65: This product contains the following ingredients for which the State of California has found to California cause cancer which would require a warning under the statute: No products were found. Proposition 65 Warnings California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. Other RegulationsEINECS: This product is not on the European Inventory of Existing Commercial Chemical Substances. Canada: Listed on Canadian Domestic Substance List (DSL). China: Listed on National Inventory. Japan: Not listed on National Inventory (ENCS). Korea: Listed on National Inventory (KECI). Philippines: Listed on National Inventory (PICCS). Australia: Listed on AICS. WHMIS (Canada) Not controlled under WHMIS (Canada). Other Classifications This product is not classified according Not applicable. DSCL (EEC) to the EU regulations. Health Hazard HMIS (U.S.A.)1 National Fire Protection 1 Flammability 1 Association (U.S.A.) Fire Hazard 1 0 Reactivity Health Reactivity 0 Specific hazard Personal Protection C WHMIS (Canada) (Pictograms) DSCL (Europe) (Pictograms) Renex 36 TDG(Canada) (Pictograms) ADR (Europe) (Pictograms) Protective Equipment Gloves (impervious). Synthetic apron. Not applicable. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 试验1 试验方法：口服 摄入剂量： 45 mg/kg/13W-C 测试对象：啮齿动物-鼠 毒性类型： MutipleDose 毒性作用：肝脏重量的变化 试验2 试验方法：行政上的皮肤 摄入剂量： 2 gm/4W 测试对象：啮齿动物-兔 毒性类型： SkinEyeIrrition 毒性作用：详细的毒副作用没有报告以外的其他致死剂量值 生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。 CHEMICAL IDENTIFICATION RTECS NUMBER : YD4571000 CHEMICAL NAME : Tridecanol condensed with 6 moles ethylene oxide CAS REGISTRY NUMBER : 24938-91-8 LAST UPDATED : 199710 DATA ITEMS CITED : 6 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit REFERENCE : FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 15,319,1977 ** OTHER MULTIPLE DOSE TOXICITY DATA ** TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 45 gm/kg/13W-C TOXIC EFFECTS : Liver - changes in liver weight REFERENCE : FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 15,319,1977 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2586 No. of Facilities: 1190 (estimated) No. of Industries: 8 No. of Occupations: 17 No. of Employees: 8519 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X9937 No. of Facilities: 1559 (estimated) No. of Industries: 27 No. of Occupations: 34 No. of Employees: 46705 (estimated) No. of Female Employees: 9820 (estimated)

安全

• 个人防护装备: Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
• 危险品运输编码: NONH for all modes of transport
• RTECS号: YD4571000