5934-69-0

• 常用中文名：1-ADAMANTACOYLDIAZOMETHANE
• 常用英文名：1-ADAMANTACOYLDIAZOMETHANE
• CAS号：5934-69-0
• 分子式：C₁₂H₁₆N₂O
• 分子量：204.26800
• 发布时间：2017-03-26 09:28:46
• 更新时间：2024-01-22 21:36:25

名称

• 英文名: (Z)-1-(1-adamantyl)-2-diazonioethenolate
• 英文别名: 1-Adamantacoyldiazomethane; 1-(adamantan-1-yl)-2-diazoethanone; 1-(1-Adamantyl)-2-diazo-1-ethanone; 1-adamantyl diazomethyl ketone; 1-(1-adamantyl)-2-diazoethanone; 2-diazo-1-(1-adamantyl)ethanone; Ketone,1-adamantyl diazomethyl; 2-oxo-2-(adamantan-1-yl)diazoethane; (1-Adamantanecarbonyl)diazomethane; Damantoyldiazomethane; 1-adamantylcarbonyldiazomethane

物化性质

• 分子式: C₁₂H₁₆N₂O
• 分子量: 204.26800
• 精确质量: 204.12600
• PSA: 51.21000
• LogP: 3.32778

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : OB1074000 CHEMICAL NAME : Ketone, 1-adamantyldiazo methyl CAS REGISTRY NUMBER : 5934-69-0 LAST UPDATED : 199712 DATA ITEMS CITED : 1 MOLECULAR FORMULA : C12-H16-N2-O MOLECULAR WEIGHT : 204.30 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD - Lethal dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : >600 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : PCJOAU Pharmaceutical Chemistry Journal (English Translation). Translation of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No.1- 1967- Volume(issue)/page/year: 8,396,1974

安全

• 海关编码: 2927000090

合成路线

186581-53-3 828-51-3 ~82% 5934-69-0

文献：Nicolaou; Baran, Phil S.; Zhong, Yong-Li; Choi, Ha-Soon; Fong, Kin Chiu; He, Yun; Yoon, Won Hyung Organic Letters, 1999 , vol. 1, # 6 p. 883 - 886

186581-53-3 2094-72-6 ~85% 5934-69-0

文献：Brueckmann, Ralf; Schneider, Klaus; Maas, Gerhardt Tetrahedron, 1989 , vol. 45, # 17 p. 5517 - 5530

768-90-1 ~% 5934-69-0

文献：Liu, Mingshun; Chen, Yaqing; Fu, Nanyan Synthetic Communications, 2013 , vol. 43, # 7 p. 1055 - 1062

828-51-3 ~% 5934-69-0

文献：Liu, Mingshun; Chen, Yaqing; Fu, Nanyan Synthetic Communications, 2013 , vol. 43, # 7 p. 1055 - 1062

84645-45-4 2094-72-6 ~% 5934-69-0

文献：Sekiguchi, Akira; Sato, Takashi; Ando, Wataru Chemistry Letters, 1983 , p. 1083 - 1084

海关

海关编码	2927000090
中文概述	2927000090 其他重氮化合物、偶氮化合物等（包括氧化偶氮化合物）. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%