e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Total synthesis of cystothiazoles A and C

DR Williams, S Patnaik, MP Clark

Index: Gompper, Rudolf; Vogt, Hans-Hubert Chemische Berichte, 1981 , vol. 114, # 8 p. 2866 - 2883

Full Text: HTML

Citation Number: 47

Abstract

... proceeded in a solvent mixture of N,N'-dimethylpropyleneurea (DMPU) and diethyl ether (1:1 by volume), giving an 85% yield of E/Z-methyl ethers (8:1 ratio ... Spots were visualized under UV light and/or staining with ethanolic p-anisaldehyde or ceric ammonium molybdate. ...

4-Methoxyphenylacetone Structure

4-Methoxyphenyl...

Dimethyl sulfate Structure

Dimethyl sulfate

~%

3-(4-methoxyphenyl)butan-2-one Structure

3-(4-methoxyphe...

N/A Structure

methyl 2-(4-methoxyphenyl)-3-oxobutanoate Structure

methyl 2-(4-met...

~%

3-(4-methoxyphenyl)butan-2-one Structure

3-(4-methoxyphe...

methyl 3-(4-methoxyphenyl)-2-methyloxirane-2-carboxylate Structure

methyl 3-(4-met...

~%

3-(4-methoxyphenyl)butan-2-one Structure

3-(4-methoxyphe...

3-Phenylpyruvic acid methyl ester Structure

3-Phenylpyruvic...

Dimethyl sulfate Structure

Dimethyl sulfate

~%

methyl 2-methoxy-3-phenylprop-2-enoate Structure

methyl 2-methox...

Dimethyl sulfate Structure

Dimethyl sulfate

Acetanisole Structure

~%

1-methoxy-4-(1-methoxyethenyl)benzene Structure

1-methoxy-4-(1-...

4'-Methoxypropiophenone Structure

4'-Methoxypropi...

4'-Methylacetophenone Structure

4'-Methylacetop...

Dimethyl sulfate Structure

Dimethyl sulfate

~%

1-(1-methoxyethenyl)-4-methylbenzene Structure

1-(1-methoxyeth...

4-Methylpropiophenone Structure

4-Methylpropiop...

Terephthalonitrile Structure

Terephthalonitrile

ETHYLMAGNESIUM BROMIDE Structure

ETHYLMAGNESIUM ...

~%

4-Propanoylbenzonitrile Structure

4-Propanoylbenz...

Acetophenone Structure

Dimethyl sulfate Structure

Dimethyl sulfate

~%

1-methoxyethenylbenzene Structure

1-methoxyetheny...

Phenyl ethyl ketone Structure

Phenyl ethyl ketone

Dimethyl sulfate Structure

Dimethyl sulfate

3-OXO-3-PHENYL-PROPIONALDEHYDE Structure

3-OXO-3-PHENYL-...

~%

3-methoxy-3-phenyl-prop-2-enal Structure

3-methoxy-3-phe...

1-(4-Chlorophenyl)ethanone Structure

1-(4-Chlorophen...

Dimethyl sulfate Structure

Dimethyl sulfate

~%

4'-Chloropropiophenone Structure

4'-Chloropropio...

Benzene,1-chloro-4-(1-methoxyethenyl)- Structure

Benzene,1-chlor...

UNII:FDN17EXK1J Structure

UNII:FDN17EXK1J

4-Methoxybenzaldehyde Structure

4-Methoxybenzal...

~%

methyl 3-(4-methoxyphenyl)-2-methyloxirane-2-carboxylate Structure

methyl 3-(4-met...

Dimethyl sulfate Structure

Dimethyl sulfate

Phenylacetone Structure

~%

2-Butanone, 3-phenyl- Structure

2-Butanone, 3-p...

2-methoxyprop-1-enylbenzene Structure

2-methoxyprop-1...

Dimethyl sulfate Structure

Dimethyl sulfate

Phenylacetone Structure

~%

2-Butanone, 3-phenyl- Structure

2-Butanone, 3-p...

2-methoxyprop-1-enylbenzene Structure

2-methoxyprop-1...

4-Methylpropiophenone Structure

4-Methylpropiop...

Dimethyl sulfate Structure

Dimethyl sulfate

~%

2,4'-dimethylpropiophenone Structure

2,4'-dimethylpr...

1-(1-methoxyprop-1-en-1-yl)-4-methylbenzene Structure

1-(1-methoxypro...

4-Methylpropiophenone Structure

4-Methylpropiop...

methyl iodide Structure

~%

2,4'-dimethylpropiophenone Structure

2,4'-dimethylpr...

1-(1-methoxyprop-1-en-1-yl)-4-methylbenzene Structure

1-(1-methoxypro...

1-(4-Bromophenyl)propan-1-one Structure

1-(4-Bromopheny...

Dimethyl sulfate Structure

Dimethyl sulfate

~%

1-(4-Bromophenyl)-2-methyl-1-propanone Structure

1-(4-Bromopheny...

1-bromo-4-(1-methoxyprop-1-en-1-yl)benzene Structure

1-bromo-4-(1-me...

Dimethyl sulfate Structure

Dimethyl sulfate

Methyl 2-phenylacetate Structure

Methyl 2-phenyl...

~%

methyl 2-phenylpropionate Structure

methyl 2-phenyl...

Methyl acetoacetate Structure

Methyl acetoacetate

Dimethyl sulfate Structure

Dimethyl sulfate

~%

methyl 3-methoxy-2-butenoate Structure

methyl 3-methox...

methyl 2-methyl-3-oxobutanoate Structure

methyl 2-methyl...

1-[4-(dimethylamino)phenyl]propan-1-one Structure

1-[4-(dimethyla...

Dimethyl sulfate Structure

Dimethyl sulfate

~%

1-[4-(dimethylamino)phenyl]-2-methylpropan-1-one Structure

1-[4-(dimethyla...

4-(1-methoxyprop-1-en-1-yl)-N,N-dimethylaniline Structure

4-(1-methoxypro...

Dimethyl sulfate Structure

Dimethyl sulfate

1-Phenylbutane-1,3-dione Structure

1-Phenylbutane-...

~%

2-methyl-1-phenylbutane-1,3-dione Structure

2-methyl-1-phen...

4-methoxy-4-phenylbut-3-en-2-one Structure

4-methoxy-4-phe...

4-methylphenylacetone Structure

4-methylphenyla...

Dimethyl sulfate Structure

Dimethyl sulfate

~%

3-(4-methylphenyl)butan-2-one Structure

3-(4-methylphen...

N/A Structure

p-Tolualdehyde Structure

~%

3-(4-methylphenyl)butan-2-one Structure

3-(4-methylphen...

methyl 3-oxo-2-(p-tolyl)butanoate Structure

methyl 3-oxo-2-...

~%

3-(4-methylphenyl)butan-2-one Structure

3-(4-methylphen...

p-Methyl-α-methyl-epoxyzimtsaeure-methylester Structure

p-Methyl-α-meth...

~%

3-(4-methylphenyl)butan-2-one Structure

3-(4-methylphen...

p-Phenylpropiophenone Structure

p-Phenylpropiop...

Dimethyl sulfate Structure

Dimethyl sulfate

~%

2-methyl-1-(4-phenylphenyl)propan-1-one Structure

2-methyl-1-(4-p...

4-(1-methoxyprop-1-en-1-yl)-1,1'-biphenyl Structure

4-(1-methoxypro...

2-METHOXYACETOPHENONE Structure

2-METHOXYACETOP...

Dimethyl sulfate Structure

Dimethyl sulfate

~%

2-methoxy-1-phenylpropan-1-one Structure

2-methoxy-1-phe...

1-allyl-2-benzylidenehydrazine Structure

1-allyl-2-benzy...

4-Fluorobenzaldehyde Structure

4-Fluorobenzaldehyde

~%

4-Fluorophenylacetone Structure

4-Fluorophenyla...

Tosylate oxygen scrambling associated with ion-pair return i...

[Goering, Harlan L.; Jones, Barry E. Journal of the American Chemical Society, 1980 , vol. 102, # 5 p. 1628 - 1633]

Photochemical reactivity of α??phenyl β, γ??enones. Singlet ...

[Koppes, Margareth J. C. M.; Beentjes, Peter C. J.; Cerfontain, Hans Recueil des Travaux Chimiques des Pays-Bas, 1988 , vol. 107, # 4 p. 313 - 324]

Ruthenium (IV) porphyrin catalyzed highly selective oxidatio...

[Wang, Zhi-Ming; Sang, Xue-Ling; Che, Chi-Ming; Chen, Jian Tetrahedron Letters, 2014 , vol. 55, # 10 p. 1736 - 1739]

Unexpected Extension of Usage of PPh 3/CBr 4, a Versatile Re...

[Gong, Wanchun; Liu, Yun; Xue, Jijun; Xie, Zhixiang; Li, Ying Chemistry Letters, 2012 , vol. 41, # 12 p. 1597 - 1599]

The Photolysis of Spiro [2.5] octa-4, 7-dien-6-one. Radical ...

[Schuster,D.I.; Polowczyk,C.J. Journal of the American Chemical Society, 1966 , vol. 88, p. 1722 - 1731]