Reactions of copper (I) halide complexes of trivalent phosphorus with vinylic halides

G Axelrad, S Laosooksathit, R Engel

Index: Axelrad, George; Laosooksathit, Surin; Engel, Robert Journal of Organic Chemistry, 1981 , vol. 46, p. 5200 - 5204

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Citation Number: 47

Abstract

The direct formation of the vinylic carbon to phosphorus bond has been accomplished via reaction of vinylic halides with copper (1) halide complexes of trialkyl phosphites. In addition, formation of varying amounts of vinylic chlorides may be observed if the reaction is performed by using vinylic bromides with copper (1) chloride complexes of trialkyl phosphites. This halogen-exchange reaction may be made synthetically useful through ...