Phosphorus, Sulfur, and Silicon

Ascorbic Acid/Iodine and Triphenylphosphine/Iodine as Reducing Agents for the As (V)[dbnd] O Group

TD Sideris, PV Ioannou

Index: Sideris, Theodore D.; Ioannou, Panayiotis V. Phosphorus, Sulfur and Silicon and the Related Elements, 2006 , vol. 181, # 5 p. 1017 - 1030

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Citation Number: 3

Abstract

The scope of ascorbic acid/iodine and triphenylphosphine/iodine in methanol for the direct reduction of arsenic (V) compounds having the As [dbnd] O group has been investigated. Ascorbic acid/iodine reduces arsonic acids, diphenylarsinic acid (but not dimethylarsinic ...

~59%

~88%

~56%

~64%

Synthesis and Structure of Intermediates in Copper-Catalyzed...

[Gillespie, Donal G.; Walker, Brian J.; Stevens, David; McAuliffe, Charles A. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 8 p. 1697 - 1703]