Tetrahedron

Etude du caractere nucleophile des radicaux lors de la reaction de transfert sur la liaison OO des peracides

J Fossey, D Lefort

Index: Fossey, Jacques; Lefort, Daniel Tetrahedron, 1980 , vol. 36, # 81 p. 1023 - 1036

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Citation Number: 23

Abstract

Peracids RC03H yield free radicals R'which react either with the peracid or with solvent giving the alcohol ROH and the hydrocarbon RH. The nucleophilic character of the free radicals was modified either by substitution of the carbon bearing the odd electron by inductive groups or by changing the free radical hybridation by the means of blocked structures such as cyclic or bicyclic free radicals. For each R, the measurement of the ratio ...

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~88%

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~10%

~97%

~41%

~8%

~3%

~1%

~0%

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~0%

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~4%

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~3%

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