Tetrahedron

Action d'un tétrafluoroborate d'oxaziridinium sur les amines et les imines

G Hanquet, X Lusinchi

Index: Hanquet, Gilles; Lusinchi, Xavier Tetrahedron, 1994 , vol. 50, # 42 p. 12185 - 12200

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Citation Number: 26

Abstract

The Oxaziridinium salt 1 derived from dihydroisoquinolin is an oxygen transfer reagent to primary amines leading to nitrosoderivatives (if R= Alkyl) or nitro compounds (if R= Aryl), to tertiary amines leading to N-oxides, and to secondary amines and imines leading to the corresponding nitrone.

~83%

~97%

~50%

~93%

~69%

~90%

~25%

~14%

~88%

~86%

~35%

Reaction of oximes with dimethyl carbonate: a new entry to 3...

[Marques, C. A.; Selva, M.; Tundo, P.; Montanari, F. Journal of Organic Chemistry, 1993 , vol. 58, # 21 p. 5765 - 5770]

Some factors affecting the site of alkylation of oxime salts

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