Double Dehydro??Diels–Alder Reactions of 1, 5??Dien??3??ynes

…, MN Paddon??Row, MS Sherburn

Index: Fallon, Thomas; Robinson, Diane E.J.E.; Willis, Anthony C.; Paddon-Row, Michael N.; Sherburn, Michael S. Chemistry - A European Journal, 2010 , vol. 16, # 3 p. 760 - 765

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Citation Number: 7

Abstract

Double Diels–Alder reactions of conjugated bis-dienes are a group of very powerful processes that allow the generation of four covalent bonds in a “one-pot” process.[1–3] Three structurally distinct conjugated bis-dienes can be envisaged (Scheme1): linear- conjugated tetraenes, in which two 1, 3-butadienes react independently;[1] cross-conjugated trienes, in which the first cycloaddition generates a new diene for reaction in the second ...