Polyhedron

Synthesis, characterization, reactivity and computational studies of new rhenium (I) complexes with thiosemicarbazone ligands derived from 4-(methylthio) …

A Núñez-Montenegro, R Carballo, JM Hermida-Ramón…

Index: Nunez-Montenegro, Ara; Carballo, Rosa; Hermida-Ramon, Jose M.; Vazquez-Lopez, Ezequiel M. Polyhedron, 2011 , vol. 30, # 12 p. 2146 - 2156

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Citation Number: 8

Abstract

N-thioamide thiosemicarbazone derived from 4-(methylthio) benzaldehyde (R= H, HL1; R= Me, HL2 and R= Ph, HL3) have been prepared and their reaction with fac-[ReX (CO) 3 (CH3CN) 2](X= Br, Cl) in methanol gave the adducts [ReX (CO) 3 (HLn)](1a X= Cl, n= 1; 1a′ X= Br, n= 1; 1b X= Cl, n= 2; 1b′ X= Br, n= 2; 1c X= Cl, n= 3; 1c′ X= Br, n= 3) in good yield. All the compounds have been characterized by elemental analysis, mass ...