An efficient procedure for the TEMPO-catalyzed oxidation of alcohols to aldehydes and ketones using ferric chloride hexahydrate as terminal oxidant

…, K Karthikeyan, PT Perumal

Index: Kumar, R. Senthil; Karthikeyan; Perumal, Paramasivan T. Canadian Journal of Chemistry, 2008 , vol. 86, # 7 p. 720 - 725

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Citation Number: 10

Abstract

A simple, efficient procedure for the oxidation of alcohols by catalytic 2, 2, 6, 6-tetramethyl- piperidyl-1-oxy (TEMPO) was developed using FeCl3⊙ 6H2O as the terminal oxidant. The reaction gives high yield of the corresponding aldehydes and ketones with no over oxidation to the acid. Key words: oxidation, TEMPO, FeCl3⊙ 6H2O.

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