An Easy Route to (Hetero) arylboronic Acids

…, M Albini, J Rouden, J Blanchet

Index: Erb, William; Hellal, Akila; Albini, Mathieu; Rouden, Jacques; Blanchet, Jerome Chemistry - A European Journal, 2014 , vol. 20, # 22 p. 6608 - 6612

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Citation Number: 21

Abstract

Abstract An unprecedented spontaneous reactivity between diazonium salts and diboronic acid has been unveiled, leading to a versatile arylboronic acid synthesis directly from (hetero) arylamines. This fast reaction (35 min overall) tolerates a wide range of functional groups and is carried out under very mild conditions. The radical nature of the reaction mechanism has been investigated.

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