Generation, reactions, direct observation, and kinetics of decafluorodiphenylcarbene

H Tomioka, K Mizutani, K Matsumoto…

Index: Tomioka, Hideo; Mizutani, Kenzoh; Matsumoto, Kenji; Hirai, Katsuyuki Journal of Organic Chemistry, 1993 , vol. 58, # 25 p. 7128 - 7134

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Citation Number: 17

Abstract

Bis (pentafluoropheny1) diazomethane (la) was prepared, and reactivities of perfluorodiphenylcarbene (2a) generated by photolysis of la were investigated not only in terms of product analysis but also by using matrix isolation spectroscopy as well as laser flash photolysis techniques. Product distributions observed in the reactions of 2a in benzene, cyclohexane, and trans-1, 2-dichloroethylene suggested that 2a reacted with ...