A new method for the reduction of isocyanates to isocyanides

JE Baldwin, JC Bottaro, PD Riordan…

Index: Baldwin, Jack E.; Bottaro, Jeffrey C.; Riordan, Peter D.; Derome, Andrew E. Journal of the Chemical Society, Chemical Communications, 1982 , # 16 p. 942 - 943

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Citation Number: 9

Abstract

Both diphenyl-t-butylsilyl-lithium and trichlorosilane-triethylamine reduce isocyanates to isocyanides in high yield under mild conditions. ... The literature contains few methods for reducing isocyanates to isocyanides, equation ( l). While simple phosphines and ... Published on 01 January 1982. Downloaded by google on 21/02/2016 10:41:00. ... View Article Online / Journal Homepage / Table of Contents for this issue ... 7 The use of di-isopropylethylamine gives slightly ...