Journal of the American Chemical Society

Organic Syntheses by Means of Noble Metal Compounds. XIII. 1 Carbonylation of Butadiene-and Isoprene-Palladium Chloride Complexes

J Tsuji, S Hosaka

Index: Tsuji,J.; Hosaka,S. Journal of the American Chemical Society, 1965 , vol. 87, p. 4075 - 4079

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Citation Number: 35

Abstract

Introduction In a previous paper of this series, 2 we reported the reaction of? r-allylpalladium chloride (I) with carbon monoxide in ethanol to form ethyl 3-butenoate (11). The reaction was assumed to proceed through the formation of acylpalladium dicarbonyl chloride, by analogy with carbonylations catalyzed by nickel carbonyl. s