Huang-Minlon Reduction of Acetylenic Keto Acids

K Sisido, M Kawanisi, M Kiyono…

Index: Sisido,K. et al. Journal of Organic Chemistry, 1964 , vol. 29, p. 2968 - 2971

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Citation Number: 3

Abstract

In a previous Sotel the migration of terminal double bond under the strongly alkaline condition was described. When 7-keto-16-heptadecenoic acid was subjected to the Huang- Jlinlon reduction, an isomeric mixture of 15heptadecenoic acids was obtained. Similar result was also reported by Hiinig and Eckart, 2 and according to them IBheptadecenoic acid could be obtained by substituting triethanolaminea for diethylene glycol as the solvent.