Probing the Nature and Extent of Stabilization within Foiled Carbenes: Homoallylic Participation by a Neighboring Cyclopropane Ring

IM Apeland, H Kählig, E Lorbeer…

Index: Christl, Manfred; Herzog, Clemens; Kemmer, Petra Chemische Berichte, 1986 , vol. 119, # 10 p. 3045 - 3058

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Abstract

... Volume: Page: ... 2013, 78 (10), pp 4879 ... Hoffmann coined the term “foiled carbenes” for a special class of singlet carbenes.(1, 2) These reactive species are stabilized to some degree by electron donation from an intramolecular π-bond into the empty p-orbital of ...