Journal of organometallic chemistry

Chemoselektive mono-und disilyletherbildung aus tertiären und sekundären silanen

L Horner, J Mathias

Index: Horner, Leopold; Mathias, Johann Journal of Organometallic Chemistry, 1985 , vol. 282, p. 155 - 174

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Citation Number: 2

Abstract

Abstract Tertiary and secondary silanes are O-selective. With alcohols the corresponding silyl ethers are formed. Cesium fluoride/imidazole (CsF/Im) is a better activating system than CsF alone. Primary OH groups are silylated remarkably faster under CsF/Im activation than secondary OH groups. Tertiary alcohols do not react.