The Journal of Organic Chemistry

A Molybdenum-Catalyzed Oxidative System Forming Oxazines (Hetero-Diels-Alder Adducts) from Primary Aromatic Amines, Hydrogen Peroxide, and Conjugated …

ER Møller, KA Jørgensen

Index: Moller, Eval Rud; Jorgensen, Karl Anker Journal of Organic Chemistry, 1996 , vol. 61, # 17 p. 5770 - 5778

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Citation Number: 20

Abstract

The development of a new molybdenum-catalyzed procedure for the formation of oxazines hetero-Diels-Alder adducts from primary aromatic amines, hydrogen peroxide, and conjugated dienes is presented. The method is based on a molybdenum-peroxo complex, which in the presence of hydrogen peroxide as the terminal oxidant selectively catalyzes the oxidation of primary aromatic amines to the corresponding dienophilic nitroso compounds. ...