Indian Journal of Chemistry B

Environmentally Benign Michael and Claisen Schmidt Reaction of Aromatic Carbonyl Compounds by Alkaline Polyionic Resin

V Jaitak, VK Kaul, P Das

Index: Jaitak, Vikas; Kaul; Das, Pralay Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2013 , vol. 52, # 8 p. 1137 - 1145

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Abstract

Abstract: A regioselective Michael reaction between aryl methyl ketones and α, β- unsaturated compounds has been carried out using basic polyionic resin as a reusable reagent. Results indicate that the reaction proceeds in consecutive manner as double Michael (27-65%) and triple Michael (40-45%) products with overall yields of 55-80%. Moreover, A-2XMP resin has also been applied on Claisen Schmidt condensations of ...