Tetrahedron letters

Studies on the effects of substituents on rate enhancements in intramolecular diels-alder reactions: Reasons for the gem-dimethyl effect

ME Jung, J Gervay

Index: Jung, Michael E.; Gervay, Jacquelyn Tetrahedron Letters, 1988 , vol. 29, # 20 p. 2429 - 2432

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Citation Number: 67

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Comparison of the rates of cyclization of a series of 2-furfuryl methyl fumarates leads to the conclusion that the gem-dimethyl effect is due primarily to higher population of reactive rotamers. ... Comparison of the rates of cyclization of a series of the 2-furfuryl methyl fumarates 3 (prepared from ...