Chemical Communications

Ruthenium-catalyzed transformation of alkenyl triflates to alkenyl halides

E Shirakawa, Y Imazaki, T Hayashi

Index: Shirakawa, Eiji; Imazaki, Yusuke; Hayashi, Tamio Chemical Communications, 2009 , # 34 p. 5088 - 5090

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Citation Number: 12

Abstract

Alkenyl halides are versatile reagents, which not only act as efficient alkenyl electrophiles but are also readily converted to strong alkenyl nucleophiles upon treating with a metal such as magnesium or lithium. Synthesis of alkenyl halides 1 from alkenyl triflates, which can be prepared regioselectively from readily available ketones or aldehydes, 2,3 is beneficial but no facile and general way has been reported. 4 Considering their high reactivity towards alkenyl triflates, 5 transition ...