Russian Journal of General Chemistry

Study of reaction of isomeric acetoxytoluenes with ozone in liquid phase in the presence of manganese bromide catalyst

AG Galstyan, AA Sedykh

Index: Galstyan; Sedykh Russian Journal of General Chemistry, 2010 , vol. 80, # 5 p. 948 - 952

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Abstract

Abstract The kinetics of the ozone reaction with isomeric acetoxytoluenes in acetic anhydride in the presence of sulfuric acid and mixed manganese bromide catalyst was studied. Under these conditions it is possible to stop the oxidation process at the stage of formation of hydroxybenzaldehydes in the form of the respective acetoxybenzylidendiacetates (63–70%). The reaction products contain also ...