Formation of Aryl??and Benzylboronate Esters by Rhodium??Catalyzed C− H Bond Functionalization with Pinacolborane

S Shimada, AS Batsanov, JAK Howard…

Index: Angewandte Chemie - International Edition, , vol. 40, # 11 p. 2168 - 2171

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Citation Number: 261

Abstract

... Angewandte Chemie: Previous article in issue: A Large 24-Membered-Ring Germanate Zeolite-Type Open-Framework Structure with Three ... View issue TOC Volume 113, Issue 11 June 1, 2001 Pages 2226–2229. ... 40 °C, 2×1 mL) and dried in vacuo to give 2 (218 mg; 79 % yield ...

 Related Synthetic Route
Toluene Structure

108-88-3

Toluene

Pinacolborane Structure

25015-63-8

Pinacolborane

~%

4,4,5,5-Tetramethyl-2-(p-tolyl)-1,3,2-dioxaborolane Structure

195062-57-8

4,4,5,5-Tetrame...

4,4,5,5-Tetramethyl-2-(2-methylphenyl)-1,3,2-dioxaborolane Structure

195062-59-0

4,4,5,5-Tetrame...

Detail
p-Xylene Structure

106-42-3

p-Xylene

Pinacolborane Structure

25015-63-8

Pinacolborane

~%

4,4,5,5-TETRAMETHYL-2-(4-METHYLBENZYL)-1,3,2-DIOXABOROLANE Structure

356570-52-0

4,4,5,5-TETRAME...

2-(2,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Structure

356570-53-1

2-(2,5-dimethyl...

Pinacolborane Structure

25015-63-8

Pinacolborane

benzene Structure

71-43-2

benzene

~20%

4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane Structure

24388-23-6

4,4,5,5-Tetrame...

Bis(pinacolato)diboron Structure

73183-34-3

Bis(pinacolato)...

Toluene Structure

108-88-3

Toluene

Pinacolborane Structure

25015-63-8

Pinacolborane

~%

4,4,5,5-Tetramethyl-2-(p-tolyl)-1,3,2-dioxaborolane Structure

195062-57-8

4,4,5,5-Tetrame...

4,4,5,5-Tetramethyl-2-(2-methylphenyl)-1,3,2-dioxaborolane Structure

195062-59-0

4,4,5,5-Tetrame...

Detail
Pinacolborane Structure

25015-63-8

Pinacolborane

benzene Structure

71-43-2

benzene

~7%

4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane Structure

24388-23-6

4,4,5,5-Tetrame...

Bis(pinacolato)diboron Structure

73183-34-3

Bis(pinacolato)...

Toluene Structure

108-88-3

Toluene

Pinacolborane Structure

25015-63-8

Pinacolborane

~%

4,4,5,5-Tetramethyl-2-(p-tolyl)-1,3,2-dioxaborolane Structure

195062-57-8

4,4,5,5-Tetrame...

4,4,5,5-Tetramethyl-2-(2-methylphenyl)-1,3,2-dioxaborolane Structure

195062-59-0

4,4,5,5-Tetrame...

Detail

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