e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Journal of the American Chemical Society

Electrophilic cleavage of cyclopropanes. Acetolysis of alkylcyclopropanes

KB Wiberg, SR Kass

Index: Journal of the American Chemical Society, , vol. 107, # 4 p. 988 - 995

Full Text: HTML

Citation Number: 47

Abstract

... Contribution from the Department of Chemistry, Yale University, New Haven, Connecticut 0651 1. Received June 14, 1984 ... Our interest in the subject has led us to carry out kinetic, tracer, and theoretical investigations of the acetolysis of a ... 0 1985 American Chemical Societv I , , - ...

1,1-dimethylcyclopropane Structure

1,1-dimethylcyc...

acetic acid Structure

~9%

2-Methylbut-2-ene Structure

2-Methylbut-2-ene

T-PENTYL ACETATE Structure

T-PENTYL ACETATE

Detail

Cyclopropane,1,1,2-trimethyl- Structure

Cyclopropane,1,...

acetic acid Structure

~6%

tetramethylethylene Structure

tetramethylethylene

2-methyl-2-pentene Structure

2-methyl-2-pentene

Detail

methylcyclopropane Structure

methylcyclopropane

acetic acid Structure

~10%

1-Butene Structure

2-butene Structure

Detail

1,1,2,2-Tetramethylcyclopropane Structure

1,1,2,2-Tetrame...

acetic acid Structure

~6%

1-Pentene,2,4-dimethyl- Structure

1-Pentene,2,4-d...

2-Pentene,2,4-dimethyl- Structure

2-Pentene,2,4-d...

Detail

Cyclopropane,1,1,2-trimethyl- Structure

Cyclopropane,1,...

acetic acid Structure

~7%

tetramethylethylene Structure

tetramethylethylene

2-methyl-2-pentene Structure

2-methyl-2-pentene

Detail

1,1,2,2-Tetramethylcyclopropane Structure

1,1,2,2-Tetrame...

acetic acid Structure

~63%

1-Pentene,2,4-dimethyl- Structure

1-Pentene,2,4-d...

2-Pentene,2,4-dimethyl- Structure

2-Pentene,2,4-d...

Detail

Cyclopropane,1,1,2-trimethyl- Structure

Cyclopropane,1,...

acetic acid Structure

~47%

tetramethylethylene Structure

tetramethylethylene

2-methyl-2-pentene Structure

2-methyl-2-pentene

Detail

methylcyclopropane Structure

methylcyclopropane

acetic acid Structure

~67%

1-Butene Structure

2-butene Structure

Detail

1,1,2,2-Tetramethylcyclopropane Structure

1,1,2,2-Tetrame...

acetic acid Structure

~17%

1-Pentene,2,4-dimethyl- Structure

1-Pentene,2,4-d...

2-Pentene,2,4-dimethyl- Structure

2-Pentene,2,4-d...

Detail

Hydrogenation with anthranilic acid anchored, polymer-bound ...

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Selectivity patterns in heterogeneously catalyzed hydrogenat...

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Reducing Characteristics of Borohydride Exchange Resin-CuSO4...

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Journal of the American Chemical Society, Vol. 63, 1941: The...

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