Palladium-catalyzed oxidative carbonylation of alkyl and aryl indium reagents with CO under mild conditions

Y Zhao, L Jin, P Li, A Lei

Index: Zhao, Yingsheng; Jin, Liqun; Li, Peng; Lei, Aiwen Journal of the American Chemical Society, 2008 , vol. 130, # 29 p. 9429 - 9433

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Citation Number: 57

Abstract

CO now can react with organoindium reagents. A novel palladium-catalyzed oxidative carbonylation reaction of organoindium reagents by CO gas with desyl chloride as oxidant was developed in supplementation with the classical methods for preparation of carboxylic acid derivatives. Primary, secondary alkyl indium reagents with β-hydrogens and aryl indium reagents were suitable substrates, and the reaction could be carried out at 60° C under 50 ...