Silylamides of group IVA and IVB elements with spirobicycloheptane structure

H Bürger, W Geschwandtner, GR Liewald

Index: Buerger, H.; Geschwandtner, W.; Liewald, G.R. Journal of Organometallic Chemistry, 1983 , vol. 259, # 2 p. 145 - 156

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Citation Number: 31

Abstract

Spirocyclic metal silylamides with spiro[3.3]heptane structure, M′  Si, Ge, Sn, Ti, Zr and Hf, have been prepared. Except for the Si derivative, the synthesis involved the reaction of the appropriate M′Cl 4 with Me 3 SiN(M)SiMe 2 -N(M)SiMe 3 , M  Li, Na. The M′  Si ...