Kinetics and mechanism of the C-alkylation of nitroalkane anions by 1-alkyl-2, 4, 6-triphenylpyridiniums: a nonchain reaction with radicaloid characteristics

AR Katritzky, MA Kashmiri, GZ De Ville…

Index: Katritzky, Alan R.; Kashmiri, M. Akram; Ville, George Z. de; Patel, Ranjan C. Journal of the American Chemical Society, 1983 , vol. 105, # 1 p. 90 - 96

Full Text: HTML

Citation Number: 28

Abstract

Abstract: The C-alkylation of 2-nitropropanide by N-substituted pyridiniums is first order in each reactant in Me2S0. The effect on the rate of temperature, N substituent, leaving group, and nucleophile was studied quantitatively. Overall, the evidence excludes an SN~ ...