Geminal bis (haloorganostannanes) and their complexation as mono-and bidentate Lewis acids with dimethyl sulfoxide

…, JP Hutchinson, JR Hyde, HG Kuivila, JA Zubieta

Index: Karol, Thomas J.; Hutchinson, John P.; Hyde, Jeffrey R.; Kuivila, Henry G.; Zubieta, Jon A. Organometallics, 1983 , vol. 2, p. 106 - 114

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Citation Number: 51

Abstract

Six (chloromethylstanny1) methanes with structures CH2 (SnMe, C13-,)(SnMe, C13-,) with n= 0-3 and m= 0-2 have been prepared by chlorine-methyl exchange from bis (trimethylstanny1) methane or bis-(trivinylstanny1) methane. Four 2, 2-bis (chloromethylstannyl) propanes have been similarly prepared from 2, 2-bis (trimethylstannyl) propane. Correlations between'H and 13C magnetic resonance parameters have been ...