… . Synthesis of cyclometallated compounds with an oxygen as the donor atom. Crystal and molecular structure of (8-methylquinoline-C, N)-(1-methoxynaphthalene-8-C, …

…, H Ossor, M Pfeffer, RHA Santos, JR Lechat

Index: Dehand, J.; Mauro, A.; Ossor, H.; Pfeffer, M.; Santos, R. H. De A.; Lechat, J. R. Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. 537 - 550

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Citation Number: 45

Abstract

Abstract Treatment of 1-methoxynaphthalene (MXNH) with n-butyllithium in a diethyl ether/n- hexane solution gives 1-methoxynaphthalene-8-lithium (MXNLi) in 30% yield as an insoluble material. This compound reacts with PdCl 2 (SEt 2) 2 to give bis (1- methoxynaphthalene-8-C, O) palladium (II)(I) _and with PtCl 2 (SEt 2) 2 to give cis-and trans- (1-methoxynaphthalene-8-C, O)(1-methoxynaphthalene-8-C)(diethylsulfide) platinum (II)(II ...