Tetrahedron letters

Synthesis of organosilicon polymers by using the Lewis-acid-catalyzed trans-allylsilylation of alkynes

N Asao, H Tomeba, Y Yamamoto

Index: Asao, Naoki; Tomeba, Hisamitsu; Yamamoto, Yoshinori Tetrahedron Letters, 2005 , vol. 46, # 1 p. 27 - 30

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Citation Number: 13

Abstract

The HfCl4 catalyzed polymerization of allyl (4-ethynylphenyl) dimethylsilane () proceeded smoothly to give poly [dimethyl-(1, 4-pentadienyl) phenylsilane](), and the HfCl4 catalyzed reaction of 1-allyl-2-(4-ethynyphenyl)-1, 1, 2, 2-tetramethyldisilane () afforded poly [1, 1, 2, ...