Organometallics 2018-04-04

Epoxide-like Chemistry: 1,2-Bifunctional P-Ligands via Stereo- and Regioselective Ring Opening of an Oxaphosphirane Complex

Jan Faßbender, Niklas Künemund, Arturo Espinosa Ferao, Gregor Schnakenburg, Rainer Streubel

Index: 10.1021/acs.organomet.8b00116

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Abstract

Facile stereo- and regioselective ring opening of the oxaphosphirane complex A is presented using small molecules with differently polar E–H bonds (HCl, H2O, and NH3). The synthetic potential of the thus obtained novel 1,2-bifunctional ligands B is illustrated in cyclocondensation reactions, leading to the novel heterocyclic P-ligands C.