Olusola Oyedele Ojelere, David Graf, Tim Ludwig, Nicolas Vogt, Axel Klein, Sanjay Mathur
Index: 10.1039/C8DT00848E
Full Text: HTML
Vanadium (II) oxide nanostructures are promising materials for supercapacitors and electrocatalysis because of their excellent electrochemical properties and high surface area. In this study, new homoleptic vanadium (III) complexes with bi-dentate O, N-chelating heteroarylalkenol ligands (DmoxCH=COCF3, PyCH=COCF3 and PyN=COCF3) were synthesized and successfully transformed by reductive conversion into VO nanowires. Chemical identity of V(III) complexes and their redox behaviour was unambiguously established by single crystal X-ray diffraction studies, cyclovoltammetry, spectrometric studies and DFT calculations. Transformation to metastable VO phase was verified by powder X-ray diffraction and thermo-gravimetry. Transmission electron microscopy and X-ray photoelectron spectroscopy data confirmed the morphology and chemical composition of VO nanostructures respectively.
New coordination networks containing trinuclear lanthanide c...
2018-04-13 [10.1039/C7DT02541F] |
Three new types of transition metal carboranylamidinate comp...
2018-04-13 [10.1039/C8DT01064A] |
Outstanding Reviewers for Dalton Transactions in 2017
2018-04-13 [10.1039/C8DT90063A] |
Cyclometalated iridium(III) complexes induce mitochondria-de...
2018-04-13 [10.1039/C8DT00783G] |
Bond Energy, Site Preferential Occupancy and Eu2+/3+ Co-dopi...
2018-04-13 [10.1039/C8DT00749G] |
Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer
Copyright © 2024 ChemSrc All Rights Reserved