Synthesis of aceanthrylene

BF Plummer, ZY Al-Saigh, M Arfan

Index: Plummer, B. F.; Al-Saigh, Z. Y.; Arfan, M. Journal of Organic Chemistry, 1984 , vol. 49, # 11 p. 2069 - 2071

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Citation Number: 23

Abstract

thesized from l-bicyclo [2.2. 2] octyl nitrile by Hartzler's method. Ig Unsymmetrical ketones were obtained by cuprous chloride catalyzed condensation of acid chlorides with organomagnesium compounds. 20 Alcohol 2 was prepared by the addition of tertbutyllithium to di-l-bicyclo [2.2. 2] octyl ketone in ether. All other alcohols were obtained by the one-pot Barbier-type addition of alkyl halides to ketones in the presence of lithium metal. 21 ...