Hydrogen bonding in fluoro alcohols

WJ Middleton, RV Lindsey

Index: Middleton; Lindsey Journal of the American Chemical Society, 1964 , vol. 86, p. 4948,4950

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Citation Number: 204

Abstract

Aliphatic alcohols that contain a high percentage of fluorine are more acidic than the corresponding fluorinefree alcohols' and thus would be expected to be stronger hydrogen- bonding acids2 The most pronounced effects would be observed in alcohols containing fluorine bonded directly to the a-carbon. One such alcohol, perfluorocyclobutanol, has been prepared, and nmr studies indicate that it is internally hydrogen bonded. However, this ...