Studies on transannulation reactions across a nine-membered ring: the synthesis of natural product-like structures

M Iqbal, RJG Black, J Winn, AT Reeder…

Index: Organic and Biomolecular Chemistry, , vol. 9, # 14 p. 5062 - 5078

Full Text: HTML

Citation Number: 7

Abstract

... Chem., 2011, 9, 5062-5078 Show Compounds Show Chemical Terms. ... This dilemma was highlighted by the early days of Taxol chemistry, where the majority of the analogues ... in nine-membered ring 3cyclisation to 4 lacks a key eclipsing interaction between the Me(9) and ...