Hexamethylsilirane: I. Preparation, characterization and thermal decomposition

D Seyferth, DC Annarelli, SC Vick…

Index: Seyferth, Dietmar; Annarelli, Dennis C.; Vick, Steven C.; Duncan, Don P. Journal of Organometallic Chemistry, 1980 , vol. 201, # 1 p. 179 - 195

Full Text: HTML

Citation Number: 46

Abstract

Abstract Hexamethylsilirane has been prepared by the action of magnesium on dimethyl-bis (α-bromoisopropyl) silane in tetrahydrofuran (THF) solution. It was found to be highly reactive toward atmospheric oxygen and moisture and to decompose when heated in solution at 60–75 C. Its decomposition results in the extrusion of dimethylsilylene which may add to the tetramethylethylene produced in the decomposition to regenerate the silirane, ...